邻菲罗啉型示踪剂配体的合成与理论计算  

Synthesis and Theoretical Calculation of Phenanthroline-based Tracer Ligand

作　　者：李子甲[1] 王敏健 吴雪鹏 吴一宁[2] 焦保雷[1] 王洋[2] 

机构地区：[1]中国石油化工股份有限公司西北油田分公司,新疆乌鲁木齐830011 [2]中国石油大学(华东),山东青岛266580

出　　处：《当代化工》2017年第12期2416-2419,共4页Contemporary Chemical Industry

基　　金：大型油气田及煤层气开发国家科技重大专项<缝洞型油藏堵调及靶向酸压工艺技术>;2016ZX05014-005

摘　　要：多轮次调剖配套示踪剂测试后,常用示踪剂背景值高,难以分析,有必要开展新型示踪剂的研究。1,10-邻菲罗啉是一类常见的刚性共轭化合物,具有良好的溶解性及较低π反键轨道能量,极易发生MLCT电子跃迁,是一类光学活性配体,同时也是合成光致发光配合物常用的一种螯合配体。主要对其5,6位修饰的对称和不对称结构化合的合成、表征及密度泛函计算作研究,该配体通过与不同金属离子螯合,有望形成系列化的示踪剂配方。After several rounds of tracing test, it＇s found that the tracer had a high background value and was difficult to analyze. So it is necessary to carry out the research of new tracer. 1,10-Phenanthroline is a kind of common rigid conjugated compound with good solubility and low π orbital energy, which is prone to MLCT electron transition. It is a kind of optically active ligand, and also is a kind of chelating ligand commonly used in photo luminescent complexes. In this paper, synthesis and characterization of phenanthroline-based tracer ligand and density functional calculations of symmetric and asymmetric structures with 5, 6 positions were studied. It＇s pointed out that a series of tracer formulations can be obtained by the chelation between the ligand and different metal ions.

关 键 词：1 10-邻菲罗啉 合成 表征 DFT 

分 类 号：TQ201[化学工程—有机化工]