Pt-H2SO4/Zr-montmorillonite： An efficient catalyst for the polymerization of octamethylcy-clotetrasiloxane, polymethylhydrosiloxane and hexamethyldisiloxane to low-hydro silicone oil  

作　　者：Yuedong Zhou Fengfu Li Junwei Liu Zhi Yun Xia Gui 

机构地区：[1]College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing 210009. China

出　　处：《Chinese Journal of Chemical Engineering》2017年第12期1771-1776,共6页中国化学工程学报（英文版）

基　　金：Supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)

摘　　要：The liquid phase ring-opening of octamethylcy-clotetrasiloxane （D4） was investigated over Pt-H2SO4/Zr- montmorillonite catalyst. Montmorillonite （Mt）, Zr-Mt, H2SO4/Mt, H2SO4/Zr-Mt and Pt-H2SO4/Zr-Mt were also detected for evaluation. The catalysts were characterized by X-ray fluorescence, X-ray diffraction, nitrogen adsorption-desorption, NH3-TPD and pyridine-FTIR measurements. In comparison to activate clay which is used in the industry of catalyst, Zr-Mt catalyst displayed stronger acidity and more excellent catalytic activity in the polymerization of D4, polymethylhydrosiloxane （DH） and hexamethyldisiloxane （MM） to low-hydro sili- cone oil. Relative to Zr-Mt, the acidity of H2SO4/Zr-Mt was noticeably improved and the catalyst exhibited a higher capability of ring-opening of D4 conversion and yield of low-hydro silicone oil. To enhance the stability of H2SO4/Zr-Mt catalyst, a small amount of metals （Pt） was doped. The nitrogen adsorption-desorption results indicated that pore textural parameters of the Pt-H2SO4/Zr-Mt had not changed with larger specific surface area. Compared with H2SO4/Zr-Mt, the total acidity of Pt-H2SO4-Zr/Mt catalyst retained, but the content of the Bransted acid increased and the content of the Lewis acid decreased. The Pt-H2SO4-Zr/Mt catalyst displayed higher catalyst reproducibility. After 40 h reaction of polymerization, the yield of low-hydro silicone oil decreased from 93% to 42% over H2SO4/Zr-Mt catalyst, while the yield of low-hydro silicone oil reduced from 93% to 78% over Pt-H2SO4/Zr-Mt catalyst. A sharp decrease in catalytic activity after 35 h of Pt-H2SO4/Zr-Mt catalyst was detected. Furthermore, Pt-H2SO4/Zr-Mt was completely regenerated under appropriate condition and appeared good repeatability in the D4, DH and MM to low-hydro silicone oil.The liquid phase ring-opening of octamethylcy-clotetrasiloxane(D_4) was investigated over Pt-H_2SO_4/Zrmontmorillonite catalyst. Montmorillonite(Mt), Zr-Mt, H_2SO_4/Mt, H_2SO_4/Zr-Mt and Pt-H_2SO_4/Zr-Mt were also detected for evaluation. The catalysts were characterized by X-ray fluorescence, X-ray diffraction, nitrogen adsorption–desorption, NH_3-TPD and pyridine-FTIR measurements. In comparison to activate clay which is used in the industry of catalyst, Zr-Mt catalyst displayed stronger acidity and more excellent catalytic activity in the polymerization of D_4, polymethylhydrosiloxane(D_4 H) and hexamethyldisiloxane(MM) to low-hydro silicone oil. Relative to Zr-Mt, the acidity of H_2SO_4/Zr-Mt was noticeably improved and the catalyst exhibited a higher capability of ring-opening of D_4 conversion and yield of low-hydro silicone oil. To enhance the stability of H_2SO_4/Zr-Mt catalyst, a small amount of metals(Pt) was doped. The nitrogen adsorption–desorption results indicated that pore textural parameters of the Pt-H_2SO_4/Zr-Mt had not changed with larger specific surface area. Compared with H_2SO_4/Zr-Mt, the total acidity of Pt-H_2SO_4-Zr/Mt catalyst retained, but the content of the Br?nsted acid increased and the content of the Lewis acid decreased. The Pt-H_2SO_4-Zr/Mt catalyst displayed higher catalyst reproducibility. After 40 h reaction of polymerization, the yield of low-hydro silicone oil decreased from 93% to 42% over H_2SO_4/Zr-Mt catalyst, while the yield of low-hydro silicone oil reduced from 93% to 78%over Pt-H_2SO_4/Zr-Mt catalyst. A sharp decrease in catalytic activity after 35 h of Pt-H_2SO_4/Zr-Mt catalyst was detected. Furthermore, Pt-H_2SO_4/Zr-Mt was completely regenerated under appropriate condition and appeared good repeatability in the D_4, D_4 Hand MM to low-hydro silicone oil.

关 键 词：Pt-H2SO4/Zr-montmorillonite Low-hydro silicone oil Catalyst Stability Regeneration 

分 类 号：O643.36[理学—物理化学] TQ324.21[理学—化学]