Zircon Trace Element Constraints on the Evolution of the Paleoproterozoic Birimian Granitoids of the West African Craton(Ghana)  

作　　者：Patrick Asamoah Sakyi Benxun Su Daniel Kwayisi Chen Chen Yang Bai Melesse Alemayehu 

机构地区：[1]Department of Earth Science, School of Physical and Mathematical Sciences, University of Ghana [2]Key Laboratory of Mineral Resources, Institute of Geology and Geophysics, Chinese Academy of Sciences [3]School of Earth Science, University of Chinese Academy of Sciences [4]School of Applied Natural Science, Applied Geology Department, Adama Science and Technology University

出　　处：《Journal of Earth Science》2018年第1期43-56,共14页地球科学学刊（英文版）

基　　金：funded by the National Natural Science Foundation of China (No. 41522203);the Youth Innovation Promotion Association, Chinese Academy of Sciences (No. 2016067)

摘　　要：The Paleoproterozoie Birimian granitoids of the West African Craton （WAC） in the northwestern part of Ghana, have been studied for their zircon trace elements concentrations to infer the source characteristics, origin, and magmatic evolution. The zircons in the granitoids have Th/U ratios ranging from 0.03 to 1.55, and display depleted light rare earth elements 0LREE） and enriched heavy rare earth elements （HREE） contents, characterized by pronounced positive to negative anomalies of Eu （Eu/Eu＊=0.14-0.98 and 1.01-6.06, respectively） and Ce （Ce/Ce＊=0.08-0.98 and 1.02-116, respectively）, which may imply that they were derived from both magmatic and hydrothermal sources. The geochemical plots of U/Yb vs. Y and Hf, the positive correlation between Hf and the other high field strength elements 0tFSE） and high rare earth elements （REE） contents, with enrichment in Ce and depletion in Eu, indicate that the granitoids possibly formed from partial melting of the crust. The trace elements characteristics （i.e., wide range of Hf, Ce/Ce＊, Th/U and Zr/Hf values） of the zircons suggest that crystallization of the magma occurred under variable oxidation states, which spanned over a longer period, implying that our data corroborate interpretations from studies of whole-rock geochemistry and geochronology on the granitoids of northwestern Ghana. This further indicates that the evolution of the Birimian granitoids in this part of the WAC occurred earlier than what had been reported in the literature.The Paleoproterozoie Birimian granitoids of the West African Craton （WAC） in the northwestern part of Ghana, have been studied for their zircon trace elements concentrations to infer the source characteristics, origin, and magmatic evolution. The zircons in the granitoids have Th/U ratios ranging from 0.03 to 1.55, and display depleted light rare earth elements 0LREE） and enriched heavy rare earth elements （HREE） contents, characterized by pronounced positive to negative anomalies of Eu （Eu/Eu＊=0.14-0.98 and 1.01-6.06, respectively） and Ce （Ce/Ce＊=0.08-0.98 and 1.02-116, respectively）, which may imply that they were derived from both magmatic and hydrothermal sources. The geochemical plots of U/Yb vs. Y and Hf, the positive correlation between Hf and the other high field strength elements 0tFSE） and high rare earth elements （REE） contents, with enrichment in Ce and depletion in Eu, indicate that the granitoids possibly formed from partial melting of the crust. The trace elements characteristics （i.e., wide range of Hf, Ce/Ce＊, Th/U and Zr/Hf values） of the zircons suggest that crystallization of the magma occurred under variable oxidation states, which spanned over a longer period, implying that our data corroborate interpretations from studies of whole-rock geochemistry and geochronology on the granitoids of northwestern Ghana. This further indicates that the evolution of the Birimian granitoids in this part of the WAC occurred earlier than what had been reported in the literature.

关 键 词：West African Craton GRANITOIDS ZIRCON trace elements magmatic evolution hydro-thermal alteration. 

分 类 号：P2[天文地球—测绘科学与技术]