金属有机骨架锌化合物的微波合成与荧光传感性能  

Microwave Synthesis and Fluorescence Sensing Property of the Zinc-based Metal-organic Framework

作　　者：何湘粮 黄秀玉 曾昭建 陈小利 刘琴 陈满生 

机构地区：[1]功能金属有机材料湖南省普通高等学校重点实验室,衡阳师范学院化学与材料科学学院,湖南衡阳421008

出　　处：《广东化工》2018年第3期34-35,42,共3页Guangdong Chemical Industry

基　　金：功能金属有机材料湖南省普通高校重点实验室开放基金资助项目(GN16K02);衡阳师范学院大学生科技创新性实验项目(校科字[2017]2号-7)

摘　　要：采用微波合成法制备了金属有机骨架材料1,通过IR和N2吸附对其结构进行表征,表明该材料为目标产物。此外,研究了该材料对多种溶剂的荧光作用。结果表明硝基苯的猝灭作用最强,因此该材料对芳香硝基化合物具有一定的选择性。The material 1 was synthesized by a modified microwave method, which were also characterized by IR and adsorption of N2. The results showed that all samples were the single pure phase. On the other hand, the influence of the quality with organic solvent, and nitroaromatic compounds quenching by nitroben-zene （NB） was also investigated. The experimental results exhibited that the nitrobenzene is favorable for the fluorescence quenching of compound 1, and which also shows the selective and sensitive detection of nitroaromatics.

关 键 词：金属有机骨架 荧光传感 制备 

分 类 号：O641.4[理学—物理化学]