Recent progress on multidimensional construction of helicenes  

作　　者：Wei-Bin Lin Meng Li Lei Fang Chuan-Feng Chen 

机构地区：[1]Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China [2]University of Chinese Academy of Sciences, Beijing 100049, China

出　　处：《Chinese Chemical Letters》2018年第1期40-46,共7页中国化学快报（英文版）

基　　金：the National Natural Science Foundation of China (Nos. 51373180, 21572233);the Strategic Priority Research Program of CAS(No. XDB12010400) for financial support

摘　　要：Helicenes have attracted more and more attention in the field of photoelectric materials and asymmetric catalysis for their unique Tr-conjugated screw-shaped structures and excellent chiroptical properties. However, further study and application of helicenes are based on novel idea, delicate design, and efficient synthetic methods Recent development of helicenes has witness various smart designs and approaches. In order to obtain a systematical and vivid introduction of latest development of helicenes, the idea of multidimensional construction is proposed in this review, which concludes the construction of multi- dimensions from length, extent, and height. We hope that this idea could be helpful to forecast the trend of helicene chemistry and provide the design inspiration of novel helicenes.Helicenes have attracted more and more attention in the field of photoelectric materials and asymmetric catalysis for their unique Tr-conjugated screw-shaped structures and excellent chiroptical properties. However, further study and application of helicenes are based on novel idea, delicate design, and efficient synthetic methods Recent development of helicenes has witness various smart designs and approaches. In order to obtain a systematical and vivid introduction of latest development of helicenes, the idea of multidimensional construction is proposed in this review, which concludes the construction of multi- dimensions from length, extent, and height. We hope that this idea could be helpful to forecast the trend of helicene chemistry and provide the design inspiration of novel helicenes.

关 键 词：HeliceneMultidimensional construction^r-Conjugated systemsChiralityCatalyst 

分 类 号：O6[理学—化学]