The enhanced electronic communication in ferrocenemethanol molecular cluster based on intermolecular hydrogen-bonding  

作　　者：Yifan Yang Qing Zheng Yuanyuan Yan Yao Liu Huibo Shao 

机构地区：[1]Key Laboratory of Cluster Science (Ministry of Education) and Beijing Key Laboratory of Photoelectronic and Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology

出　　处：《Chinese Chemical Letters》2018年第1期179-182,共4页中国化学快报（英文版）

基　　金：the financial support from the National Natural Science Foundation of China(No. 21173023);National 111 Project of China(No. B07012)

摘　　要：This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol （described as FcCH2OH） molecular clusters. The enhanced electronic communication in FcCH2OH clusters is confirmed and further investigated by differential-pulse voltammetry and cyclic voltammetry. A key finding is that this enhanced electronic communication increases the standard rate constant of the electron transfer process. These results will provide us with a further understanding of the electronic communication within the ferrocenyl derivariv~ which it ha^pd nn rhp inr^rmnlpcldar hvdrn^en-hnndinctThis work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol （described as FcCH2OH） molecular clusters. The enhanced electronic communication in FcCH2OH clusters is confirmed and further investigated by differential-pulse voltammetry and cyclic voltammetry. A key finding is that this enhanced electronic communication increases the standard rate constant of the electron transfer process. These results will provide us with a further understanding of the electronic communication within the ferrocenyl derivariv~ which it ha^pd nn rhp inr^rmnlpcldar hvdrn^en-hnndinct

关 键 词：Enhanced electronic communicationlntermolecular hydrogen-bondingMolecular clustersElectron transferCyclic voltammetry 

分 类 号：O6[理学—化学]