混合尖晶石型Zn_6Ga_8TiO_(20):Cr^(3+)荧光粉的合成、结构表征与发光性能  

Microstructure Characterization and Luminescent Property of Mixed Spinel Zn_6Ga_8TiO_(20):Cr^(3+) Phosphors

作　　者：郑遗凡[1,2] 张露露 王锴 潘再法 

机构地区：[1]浙江工业大学化学工程学院,杭州310014 [2]浙江工业大学分析测试中心,杭州310014

出　　处：《无机材料学报》2018年第1期9-13,共5页Journal of Inorganic Materials

基　　金：国家自然科学基金重点项目(10804099);浙江省自然科学基金(Y4110536);浙江省重点科技创新团队(2009R-50002)~~

摘　　要：采用高温固相法合成新型红色荧光粉Zn_6Ga_(8-x)TiO_(20):xCr^(3+)。用XRD、XRF和TEM对样品的成分和晶体结构进行表征,发现所合成的荧光粉为单一的混合尖晶石结构,Cr^(3+)能有效地掺杂进入基质Zn_6Ga_8TiO_(20)中,并占据八面体格位。荧光光谱分析表明,激发谱由四个峰组成,峰值分别为281、337、420和555 nm,其中281 nm对应Cr^(3+)离子的~4A_2→~4T_1(4P)跃迁,337 nm来自O^(2-)的2p轨道电子向Ga^(3+)的4s4p轨道迁移跃迁,420和555 nm分别对应Cr^(3+)离子的~4A_2→~4T_1和~4A_2→~4T_(2g)的跃迁。发射光谱是由~2E→~4A_2的跃迁辐射零声子线(689 nm,R锐线)、处于畸变的环境中Cr^(3+)发射的N线(696 nm)以及由晶格振动导致的声子伴随发射峰组成。这种荧光粉是一种可能应用在白光LED上的红色荧光粉。A novel red phosphor Zn6Ga8-xTiO20：xCr3＋ was prepared via a high temperature solid-state method. The as-prepared phosphors were examined by means of X-ray diffraction, X-ray fluorescence and transmission electron microscopy. The results showed that the synthesized phosphor had a single mixed spinel structure and Cr3＋ could be effectively doped into the host Zn6Ga8TiO20 by occupation of octahedral sites. It was showed that the excitation spectrum was composed of four bands located at 281, 337, 420 and 555 nm, respectively. The band at 281 nm corresponded to the 4A2-4T1 （4P） transition of Cr3＋ and that at 337 nm originated from the charge transfer from 2p orbitals of O2- to the 4s4p orbital of Ga3＋, while the bands at 420 and 555 nm were related to the transitions of 4A2-4T1 and 4A2-4T2g of Cr3＋ ions, respectively. The emission spectrum was composed of the zero-phonon lines corresponding to the 2E-4A2 transition of Cr3＋ （689 nm, R sharp line）, the N-line （696 nm） of Cr3＋ locating at distorted sites, and the phonon-side bands. Therefore, this phosphor can be used as a red phosphor material in white LED.

关 键 词：Zn6Ga8-xTiO20 xCr 红色荧光粉 微结构 荧光 

分 类 号：TQ174[化学工程—陶瓷工业]