苯并噁嗪功能材料的研究进展  

Preparation and Applications of Functionalized Benzoxazine-Based Materials

作　　者：冯子健 曾鸣 刘程 庞涛 徐庆玉 孟大维 顾宜[2] 

机构地区：[1]教育部纳米矿物材料及应用工程研究中心中国地质大学(武汉)材料与化学学院,湖北武汉430074 [2]高分子材料工程国家重点实验室四川大学高分子科学与工程学院,四川成都610065

出　　处：《高分子材料科学与工程》2018年第1期184-190,共7页Polymer Materials Science & Engineering

基　　金：国家教育部留学回国人员科研启动基金(教外司留[2009]1341号);高分子材料工程国家重点实验室开放基金(四川大学)(KF201106);中国地质大学(武汉)教育部纳米矿物材料及应用工程研究中心(cug 2015)项目;国家级大学生创新创业计划(2016)

摘　　要：苯并噁嗪树脂作为一种新型的热固性树脂,具有分子设计性强、热稳定性和力学性能优异、残炭率高、固化过程无小分子释放、吸水率低等优点。随着研究的深入和思路的不断拓展,研究人员逐渐将苯并噁嗪树脂从工程材料向功能材料方向发展,作为一种新型的先进功能材料,其相关研究已引起广泛关注。本文综述了近年来对苯并噁嗪树脂进行功能化研究的一系列研究工作。首先,归纳了苯并噁嗪功能材料的制备方法;其次,重点介绍了苯并噁嗪功能材料在储能、环境、医学、智能材料等领域的应用研究现状;最后,对苯并噁嗪功能材料目前存在的问题进行了概述,并对未来的发展前景做出了展望。Polybenzoxazines have a number of unique properties such as design flexibility,excellent thermal and mechanical properties,high char yield,near zero volumetric shrinkage/expansion upon polymerization,and low water absorption.Recently,the preparation of functional materials based on polybenzoxazines and their composites or using polybenzoxazines as carbonization precursors were reported.The synthesized materials are represented as a novel type of advanced functional materials and have received wide attention.Herein,a survey of the recent literatures on functionalized materials of benzoxazine were presented,with particular emphasis on the preparation and application.Firstly,varieties of routes used to produce benzoxazine-based functional materials were reviewed.Secondly,an overview of applications for these functional materials in the fields of energy storage,environment,medicine,smart material as well as other applications was summarized.Finally,listing current challenges and future perspectives for this new class of functional materials were concluded.

关 键 词：苯并噁嗪 功能化 制备 储能 

分 类 号：TQ323.1[化学工程—合成树脂塑料工业]