燃煤烟气半干法脱氯的化学动力学模拟（英文）  

Chemical kinetics simulation of semi-dry dechlorination in coal-fired flue gas

作　　者：Chang LIU Hong ZHAO Wei-ying YANG Kun-zan QIU Jian-guo YANG Zi-wen GENG Wei-ming TENG Wei-zhong YUAN Xi-jiong CHEN 

机构地区：[1]The State Key Laboratory of Clean Energy Utilization, Zhejiang University [2]Zhejiang Provincial Energy Group Co.,Ltd. [3]Zhejiang Energy Changxing Power Generation Co.,Ltd.

出　　处：《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》2018年第2期148-157,共10页浙江大学学报（英文版）A辑（应用物理与工程）

基　　金：Project supported by the Zhejiang Provincial Natural Science Foundation of China(No.LY15E060002)

摘　　要：目的:燃煤锅炉烟气中的HCl对环境、设备及脱硫系统有不利的影响,也是脱硫废水处理的难点。本文提出半干法脱氯技术,探讨其技术合理性,并研究不同因素对反应效率的影响,为进一步工程应用提供理论依据,实现燃煤烟气中HCl的脱除及脱硫废水零排放。创新点:1.提出半干法脱氯技术,将氯离子固化到飞灰中;2.脱氯后脱硫废水大幅减少,将脱硫废水作为碱基溶剂回喷到烟道中,实现脱硫废水零排放;3.建立良搅拌反应器(PSR)模型,探讨半干法脱氯过程的化学动力学反应机理与关键参数。方法:1.通过CHEMKIN构建PSR模型,模拟实际燃煤烟气组分下的半干法脱氯过程;2.通过敏感性分析,探讨SO_2与HCl之间的竞争关系(图8~10);3.通过单变量模拟,研究不同因素对反应效率的影响(图13~16)。结论:1.烟气中的SO_2对HCl的脱除存在较大竞争关系,但即使Na/Cl(摩尔比)为1时,HCl的反应效率依然可观。2.HCl的反应效率与Na/Cl呈正相关;综合考虑反应效率和运行成本,设置Na/Cl为5较为合理。3.SO_2浓度的小范围变化不会对HCl的反应效率造成显著影响。4.仅通过化学动力学模拟,烟气温度对HCl的反应效率影响不明显。5.烟气中酸性气体与NaOH在0.1 s内即可完成反应,在1 s左右达到平衡。HCl in coal-fired flue gas has adverse impact on the environment, equipment, and the flue gas desulfurization （FGD） system. The existence of HCl also increases the difficulty of the treatment of desulfurization waste water. Semi-dry dechlorination technology is put forward to attach chlorine to fly ash by spraying in alkaline solution. Simultaneously, desulphurization waste water is used as the solvent of alkali, and this could help realize the target of near-zero emission of desulfurization waste water. CHEMKIN is used to build a chemical kinetics model, which is based on the measured components of flue gas in a coal-fired power plant. NaOH is set as the alkali absorbent in the model, Both the competitive relationship of SO2 and HCl and the effects of different factors on HCl reaction effmiency are analyzed. SOs with high concentration would compete for more NaOH, but when Na/Cl （ratio in mole） is 1, the reaction efficiency of HCl achieves 22.28%, and it is positively correlated with Na/Cl. When Na/Cl surpasses 5, the reaction efficiency of HCl increases to beyond 70%. As Na/Cl continues to increase, there is a slower growth of HCl reaction efficiency and it finally achieves 100% when Na/Cl reaches 12. With a fixed value ofNa/Cl, a change of 1000 mg/m3 in SO2 concentration would change the reaction efficiency of HCl about 13%. The effect of flue temperature on HCl reaction efficiency is not significant. Acid gases in flue gas react with NaOH completely in 0.1 s and come to equilibrium after about 1 s.

关 键 词：燃煤烟气 半干法脱氯 化学动力学 竞争机理 钠氯比 CHEMKIN 

分 类 号：X773[环境科学与工程—环境工程]