New perylene diimide derivatives: stable red emission, adjustable property from ACQ to AIE, and good device performance with an EQE value of 4.93%  

作　　者：Luyi Zong Yanbin Gong Yun Yu Yujun Xie Guohua Xie Qian Peng Qianqian Li Zhen Li 

机构地区：[1]Department of Chemistry, Hubei Key Lab on Organic and Polymeric Opto-Electronic Materials, Wuhan University, Wuhan 430072, China [2]Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

出　　处：《Science Bulletin》2018年第2期108-116,共9页科学通报（英文版）

基　　金：supported by the National Natural Science Foundation of China (51673151, 61575146 and 21325416);the Open Fund of the State Key Laboratory of Luminescent Materials and Device in South China University of Technology (2017skllmd-04)

摘　　要：Perylene diimide （PDI） derivatives, due to their special opto-electronic property, have been successfully utilized in organic field-effect transistor （OFET）, solar cells, and as non-fullerene acceptor and others, while few cases in organic light-emitting diodes （OLEDs）. In this work, six perylene bisimide-based red emitters, N＇N＇-bis（2-decyltetradecyl）-1-（[1,1′：3′,1″-terphenyl]-5′-yl）perylene-3,4,9,10-diimide （STPH）, N＇N＇-bis（2-decyltetradecyl）-1,7-bis（[1,1′：3′,1″-terphenyl]-5′-yl）perylene-3,4,9,10-diimide （DTPH）, N,N＇- bis（2-decyltetradecyl）-1-（5′-phenyl-[1,1′：3′,1″-terphenyl]-4-yl）perylene-3,4,9,10-diimide （STRPH）, N,N′- bis（2-decyltetradecyl）-1,7-bis（5′-phenyl-[ 1 ,1′：3′,1＂-terphenyll-4-yl）perylene-3,4,9,10-diimide （DTRPH）, N,N′-bis（2-decyltetradecyl）-1-（4-（2,2-diphenylvinyl）phenyl）perylene-3,4,9,10-diimide/STTPE） and N,N＇- bis（2-decyltetradecyl）-1,7-bis（4-（2,2-diphenykvinyl）phenyl）perylene-3,4,9,10-diimide （DTTPE）, with the excellent chemical, thermal and photo-chemical stability, are synthesized through the convenient Suzuki coupling reaction, in which, the fluorescent properties can be modified easily from ACQ to AIE by just simply changing the bulky volume of the introduced aromatic substituents. After being fabricated into organic light-emitting diodes, STRPH exhibits the best performance with the maximum luminescence, power efficiency, current efficiency and external quantum efficiency of 1,948 cd m-2, 2.04lm W-1, 5.85 cd A-1, 4.93% at Commission Internationale de L＇Eclairage （CIE） coordinates of （0.56, 0.34）, as the result of the high efficient energy transfer and good energy match achieved in the device.Perylene diimide(PDI) derivatives, due to their special opto-electronic property, have been successfully utilized in organic field-effect transistor(OFET), solar cells, and as non-fullerene acceptor and others,while few cases in organic light-emitting diodes(OLEDs). In this work, six perylene bisimide-based red emitters, N,N''-bis(2-decyltetradecyl)-1-([1,1':3',1''-terphenyl]-5'-yl)perylene-3,4,9,10-diimide(STPH),N,N'-bis(2-decyltetradecyl)-1,7-bis([1,1':3',1''-terphenyl]-5'-yl)perylene-3,4,9,10-diimide(DTPH), N,N''-bis(2-decyltetradecyl)-1-(5'-phenyl-[1,1':3',1''-terphenyl]-4-yl)perylene-3,4,9,10-diimide(STRPH), N,N0-bis(2-decyltetradecyl)-1,7-bis(5'-phenyl-[1,1':3',1''-terphenyl]-4-yl)perylene-3,4,9,10-diimide(DTRPH),N,N0-bis(2-decyltetradecyl)-1-(4-(2,2-diphenylvinyl)phenyl)perylene-3,4,9,10-diimide(STTPE) and N,N'-bis(2-decyltetradecyl)-1,7-bis(4-(2,2-diphenylvinyl)phenyl)perylene-3,4,9,10-diimide(DTTPE), with the excellent chemical, thermal and photo-chemical stability, are synthesized through the convenient Suzuki coupling reaction, in which, the fluorescent properties can be modified easily from ACQ to AIE by just simply changing the bulky volume of the introduced aromatic substituents. After being fabricated into organic light-emitting diodes, STRPH exhibits the best performance with the maximum luminescence, power efficiency, current efficiency and external quantum efficiency of 1,948 cd m^(-2), 2.04 lm W^(-1), 5.85 cd A^(-1), 4.93% at Commission Internationale de L'Eclairage(CIE) coordinates of(0.56, 0.34),as the result of the high efficient energy transfer and good energy match achieved in the device.

关 键 词：PDI derivativesRed emittersOrganic light-emitting diodesAggregation induced emission 

分 类 号：O644.1[理学—物理化学]