高强度高透明性聚酰亚胺膜的制备与性能研究  

Preparation and Properties of Polyimide Film with High Strength and High Transparency

作　　者：汪聪茜 陈薇[1,2] 陈妤红[1] 刘继延[1,2] 尤庆亮[1,2] 胡思前[1,2] WANG Congqian1,2, CHEN Wei1,2, CHEN Yuhong1, ,LIU Jiyan1,2, YOU Qingliang1,2, HU Siqian1,2(1. Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, 2. School of Chemical and Enviromental Engineering, Jianghan University, Wuhan 430056, Chin)

机构地区：[1]江汉大学光电化学材料与器件教育部重点实验室,湖北武汉430056 [2]江汉大学化学与环境工程学院,湖北武汉430056

出　　处：《绝缘材料》2018年第3期31-34,共4页Insulating Materials

基　　金：国家高技术研究发展计划(863计划)项目(2015AA033406);武汉市人才培养计划(20141822)

摘　　要：采用4-氨基苯基-3,5-二乙基-4-氨基苯基-9,10-二氢-9-氧杂-10-磷杂菲-10-磷酰基乙烷(ADADOPPE)和2-(4-氨基苯基)-5-氨基苯并恶唑(AAPBO)以不同摩尔比与2,3,3′,4′-联苯四甲酸二酐(α-BPDA)共聚制备一系列聚酰亚胺(PI)薄膜。通过FTIR、TGA、TMA、极限氧指数仪和UV-Vis等仪器对薄膜进行结构表征及性能研究。结果表明:含ADADOPPE不对称二胺单体的PI膜比传统PI膜有出色的透明性并具有较好力学性能,其中PI-C-3薄膜的截止波长为401.5 nm,最大透过率达到82.25%,拉伸强度为136.4 MPa。A series of polyimide （PI） films were synthesized by different molar ratios of 4-amino phe- nyl-3~5-diethyl^4-amin^phenyl.9~~^-dihydro-9-oxa-10-phosphaphenanthrene-~^-ph^sph^ryl ethane （ADADOPPE） and 2-（4-aminophenyl）-5-aminobenzoxazole （AAPBO） copolymerizing with 2,3,3＇,4＇-biphenyl tetracarboxylic dianhydride （a-BPDA）. The structures and properties of the films were studied via FTIR, TGA, TMA, limit oxygen index tester and UV-Vis. The results show that the PI films with unsymmetrical diarnine monomer （ADADOPPE） have better transparency and mechanical strength than that of traditional PI film. The cut-off wavelength of PI-C-3 film is 401.5nm, the maximum transmittance is 82.25% and the tensile strength is 136.4 MPa.

关 键 词：聚酰亚胺薄膜 α-BPDA 力学性能 光学透过性 

分 类 号：TM215-3[一般工业技术—材料科学与工程] TQ323.7[电气工程—电工理论与新技术]