Twisted penta-Carbazole/Benzophenone Hybrid Compound as Multifunctional Organic Host, Dopant or Non-doped Emitter for Highly Efficient Solution-Processed Delayed Fluorescence OLEDs  

作　　者：Fangfang Wang Xudong Cao Ling Mei Xinwen Zhang Jia Hu Youtian Tao 

机构地区：[1]Key Lab for Flexible Electronics & Institute of Advanced Materials, Jiangsu National Synergistic Innovation Centre for Advanced Materials (SICAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing, Jiangsu 211816, China [2]Key Laboratory for Organic Electronics and Information Displays and Instituteof Advanced Materials, Nanjing University of Posts and Telecommunications, Wenyuan Road, Nanjing, Jiangsu 210046, China

出　　处：《Chinese Journal of Chemistry》2018年第3期241-246,共6页中国化学（英文版）

基　　金：Acknowledgement This project was financially supported by the National Natural Science Foundation of China （62474062）, the NSF of Jiangsu Province （BK20160042 and XYDXX-026） and the Foundation for the Author of National Excellent Doctoral Dissertation of China FANEDD （201436）.

摘　　要：A new multi-functional penta-carbazole/benzophenone hybrid compound 5CzBP was designed and synthesized through a simple one-step catalyst-free C--N coupling reaction by using 2,3,4,5,6-pentafluorobenzophenone and carbazole as starting materials. 5CzBP is very soluble in tetrahydro- furan （THF）, which brings an environmentally friendly device fabrication for solution-processed OLEDs instead of most widely used chlorinated solvents when 5CzBP is employed as the bulk-phase of organic host or non-doped emitter in the emissive layer. 5CzBP exhibits thermally activated delayed fluo- rescence （TADF） characteristic with relatively high triplet energy of 2.60 eV and a low bEsT of 0.01 eV. By using the new TADF material as organic host for another green TADF emitter, maximum external quantum efficiency （EQE） of 12.5% has been achieved in simple solution-processed OLED device. Besides, a maximum EQE of 8.9% and 5.7% was further obtained in TADF devices based on 5CzBP as dopant and non-doped emitter, respectively. The simultane- ously acting as efficient TADF host and non-doped TADF emitter provides the potential guidance of the future simple single-layer two-color white OLEDs based on low-cost pure organic TADF materials.A new multi-functional penta-carbazole/benzophenone hybrid compound 5CzBP was designed and synthesized through a simple one-step catalyst-free C--N coupling reaction by using 2,3,4,5,6-pentafluorobenzophenone and carbazole as starting materials. 5CzBP is very soluble in tetrahydro- furan （THF）, which brings an environmentally friendly device fabrication for solution-processed OLEDs instead of most widely used chlorinated solvents when 5CzBP is employed as the bulk-phase of organic host or non-doped emitter in the emissive layer. 5CzBP exhibits thermally activated delayed fluo- rescence （TADF） characteristic with relatively high triplet energy of 2.60 eV and a low bEsT of 0.01 eV. By using the new TADF material as organic host for another green TADF emitter, maximum external quantum efficiency （EQE） of 12.5% has been achieved in simple solution-processed OLED device. Besides, a maximum EQE of 8.9% and 5.7% was further obtained in TADF devices based on 5CzBP as dopant and non-doped emitter, respectively. The simultane- ously acting as efficient TADF host and non-doped TADF emitter provides the potential guidance of the future simple single-layer two-color white OLEDs based on low-cost pure organic TADF materials.

关 键 词：OLED thermally activated delayed fluorescence solution-process BENZOPHENONE HOST 

分 类 号：O614.33[理学—无机化学] TN873.3[理学—化学]