Synthesis,Crystal Structure and Properties of A Triphenyltin Schiff Complex with Salicylidene-2-aminophenol  

作　　者：ZHANG Fu-Xing WU Qian KUANG Dai-Zhi YU Jiang-Xi JIANG Wu-Jiu ZHU Xiao-Ming 

机构地区：[1]Department of Chemistry and Material Science,Hengyang Normal University,Key Laboratory of Functional Metal-organic Compounds of Hunan Province [2]Key Laboratory of Functional Organometallic Materials of Hengyang Normal University,College of Hunan Province,Hengyang,Hunan 421008,China

出　　处：《Chinese Journal of Structural Chemistry》2018年第2期270-276,共7页结构化学（英文）

基　　金：Supported by the Open Fund Project of Key Laboratory of Functional Organometallic Materials of Hengyang Normal University(15K017,14K014,13K105);Natural Science Foundation of Hunan Province(No.13JJ3112);Scientific&Technological Projects of Hunan Province(No.2014NK3086);Aid programs for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province;the Key Discipline of Hunan Province;Project funding for research and innovation experiment of university students in Hunan Province

摘　　要：The triphenyltin complex with salicylidene-2-aminophenol （C31H24NO2Sn, 1） has been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and X-ray single-crystal diffraction. The complex crystallizes in monoclinic system, P21/c space group with a = 1.09515（8）, b = 1.17739（8）, c = 2.29075（14） nm, β = 117.070（4）°, V = 2.6302（3） nm3, Z = 4, Dc = 1.417 g/cm3, ？ = 0.999 mm–1, F（000） = 1123, R = 0.0472 and wR = 0.1169. X-ray single-crystal diffraction showed that 1 demonstrates a one-dimensional chain structure. The quantum chemical calculation of 1 has been investigated. Complex 1 emits fluo- rescence at 558 nm and exhibits certain inhibitory activity against NCI-H460, A549 and MCF-7.The triphenyltin complex with salicylidene-2-aminophenol （C31H24NO2Sn, 1） has been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and X-ray single-crystal diffraction. The complex crystallizes in monoclinic system, P21/c space group with a = 1.09515（8）, b = 1.17739（8）, c = 2.29075（14） nm, β = 117.070（4）°, V = 2.6302（3） nm3, Z = 4, Dc = 1.417 g/cm3, ？ = 0.999 mm–1, F（000） = 1123, R = 0.0472 and wR = 0.1169. X-ray single-crystal diffraction showed that 1 demonstrates a one-dimensional chain structure. The quantum chemical calculation of 1 has been investigated. Complex 1 emits fluo- rescence at 558 nm and exhibits certain inhibitory activity against NCI-H460, A549 and MCF-7.

关 键 词：triphenyltin complex with salicylidene-2-aminophenol ORGANOTIN synthesis crystal structure vitro anticancer activity 

分 类 号：O625.632[理学—有机化学] TQ325.3[理学—化学]