Construction of a Pillared-layer Framework Based on Charge Balance:CO2 Adsorption and Luminescence  

作　　者：傅红如 朱林 王凯路 王慧芳 韩民乐 

机构地区：[1]College of Chemistry and Chemical Engineering,Luoyang Normal University

出　　处：《Chinese Journal of Structural Chemistry》2018年第3期461-466,共6页结构化学（英文）

基　　金：financially supported by the National Natural Science Foundation of China(No.21601080);the Key Scientific Research Projects of Higher Education of He'nan Province(16A150016)

摘　　要：Via the strategy of charge balance,one new pillared layered metal-organic framework [Zn2（TNB）（2-nim）]（H3TNB = 4,4？,4？？-nitrilotribenzoicacid,2-nim = 2-nitroimidazole）（1） was successfully synthesized based on mixed ligands,where binuclear [Zn2（CO2）3]~＋ cluster-based cationic layers [Zn2（TNB）]~＋ are connected by deprotonated 2-nitroimidazole.Meanwhile,CO2 adsorption bahaviors and luminescent property of compound 1 were investigated.Via the strategy of charge balance,one new pillared layered metal-organic framework [Zn2（TNB）（2-nim）]（H3TNB = 4,4？,4？？-nitrilotribenzoicacid,2-nim = 2-nitroimidazole）（1） was successfully synthesized based on mixed ligands,where binuclear [Zn2（CO2）3]~＋ cluster-based cationic layers [Zn2（TNB）]~＋ are connected by deprotonated 2-nitroimidazole.Meanwhile,CO2 adsorption bahaviors and luminescent property of compound 1 were investigated.

关 键 词：pillared-layer metal-organic frameworks charge balance CO2 adsorption luminescence 

分 类 号：O641.4[理学—物理化学]