双核Salen-Cu配合物的合成与表征及光催化性质的研究  

Synthesis, Characterization of Dinuclear Salen Copper Complex and The Study of Photocatalytic Properties

作　　者：吕振花 陈忠凯 李立军[1] Lv Zhenhua;Chen Zhongkai;Li Lijun(College of Chemistry ＆ Environmental Science, Hebei University, Baoding 071002, China)

机构地区：[1]河北大学化学与环境科学学院,河北保定071002

出　　处：《广东化工》2018年第7期58-61,64,共5页Guangdong Chemical Industry

基　　金：河北省自然科学基金(No.B 2014201174)

摘　　要：通过溶剂热的方法合成了一种双核配位聚合物[Zn_2(L-Cu)(PTA)_2(DMSO)]_n(L=N,N'-二(3-叔丁基-5-(4'-吡啶基)水杨叉基)-1,2-环己二胺),并对其进行了红外光谱、元素分析、热重分析、X-ray衍射等表征。实验数据表明该配位聚合物在光催化作用下对亚甲基蓝的降解率达95%,且可以重复利用3次。A dinuclear coordination polymer [Zn2（L-Cu）（PTA）2（DMSO）], has been synthesized by solvothermal method and characterizated by IR spectrum, elemental analysis, thermogravimetric analysis, X-ray diffraction. The experiments indicated that the photocatalytic degradation rate of the Methylene Blue by Salen copper coordination polymer was 95 % and the coordination polymer could be reused three times.

关 键 词：SALEN配合物 晶体结构 亚甲基蓝 光催化 

分 类 号：O641.4[理学—物理化学]