新型黏结剂和水性交联剂在模压可燃药筒中的应用  

Application of a New Adhesive and a Waterborne Cross-linking Agent in Molded Combustible Cartridge Cases

作　　者：田书春[1,2] 周伟良 李忠山[1] 周晓红 TIAN Shuchun;ZHOU Weiliang;LI Zhongshan;ZHOU Xiaohong(Xi＇an North Huian Chemical Industries Co. , Ltd. （Shaanxi Xi＇an, 710302;School of Chemical Engineering, Nanjing University of Science and Technology （Jiangsu Nanjing, 210094)

机构地区：[1]西安北方惠安化学工业有限公司,陕西西安710302 [2]南京理工大学化工学院,江苏南京210094

出　　处：《爆破器材》2018年第3期27-30,36,共5页Explosive Materials

摘　　要：为提高模压可燃药筒的力学强度,同时改善其燃尽性,于某定型号产品配方基础上试制了含新型黏结剂CK及水性交联剂DZ的新型模压可燃药筒,并对黏结剂与交联剂配比、试样力学强度及燃烧性能等进行了研究。结果表明,黏结剂CK和交联剂DZ优化配比后的质量分数分别为12.0%和1.5%;新型模压可燃药筒抗拉强度和最大伸长率可达到36.7 MPa和7.0%,较传统试样分别提高了46.2%和42.9%;燃烧后,烘前及烘后平均残渣质量分别降低了55.07%和64.07%;此外,上炮试验中,射击后火炮膛内也无影响装填的残渣。新型黏结剂CK和水性交联剂DZ的引入有效地提高了模压可燃药筒的力学强度及韧性,且燃尽性也有所改善。In order to improve mechanical strength and burning-off property of molded combustible cartridge cases, a new adhesive CK and a waterborne cross-linking agent DZ were added in to develop new formulation of the molded com- bustible cartridge cases. Optimum mass ratio of CK and DZ, mechanical strength and combustion performance were investi- gated. Results show that the optimum mass fraction of adhesive and cross-linking are 12.0% and 1.5% , respectively. Mechanical strength and elongation can reach to 36.7 MPa and 7.0% , which increase by 46.2% and 42.9% when compared to traditional samples. After combustion, the average residues before and after drying are decreased by 55.07% and 64.07%, respectively. Furthennore, there is no visible residue in the gun chamber after shooting on the gun test. These results indicate that the addition of the new adhesive CK and the waterborne cross-linking agent DZ significantly improve the mechanical strength, tenacity and burning-off properly of molded combustible cartridge cases.

关 键 词：模压可燃药筒 力学强度 黏结剂CK 水性交联剂 

分 类 号：TQ565[化学工程—炸药化工] TJ55[兵器科学与技术—军事化学与烟火技术]