含环己烯基脂环族二元酸酐的制备与性能研究  

Synthesis and research of a new cyclohexenyl-containing alicyclic dianhydride

作　　者：熊磊[1] 陈杰 谢琦林 胡振涛 刘峰 Xiong Lei;Chen Jie;Xie Qilin;Hu Zhentao;Liu Feng(Department of Biochemistry,College of Science and Technology, Nanchang University, Nanchang 330029;School of Chemsitry, Nanchang University, Nanchang 330031)

机构地区：[1]南昌大学科学技术学院生物化学系,南昌330029 [2]南昌大学化学学院,南昌330031

出　　处：《化工新型材料》2018年第4期108-110,共3页New Chemical Materials

基　　金：国家自然科学基金(51263014)

摘　　要：以四氢苯酐与氯化偏苯三酸酐为反应物,通过加氢还原和酯化反应两步法合成了一种新型含环己烯基脂环族二元酸酐,并对其进行了结构表征和溶解性研究。红外光谱(FT-IR)与核磁共振(1 H-NMR)均证实了目标产物被成功合成,且该二元酸酐在常规有机溶剂中具有良好的溶解性。A new cyclohexenyl-containing alicyclic dianhydride, cyclohex-4-ene-1,2-diylbis （methylene） bis （ 1, 3-dioxo-1, 3-dihydroisobenzofuran-5-carboxylate） was synthesized by reduction and esterification, starting from tetrahydrophthalic anhydride and trimellitic anhydride acid chloride.FT-IR and ^1H-NMR spectra indicated that the new cyclohexenyl-containing alicyclic dianhydride was successfully performed, and it showed good solubility in several organic solvents.

关 键 词：二元酸酐 脂环族 制备 性能 

分 类 号：TQ235[化学工程—有机化工]