三维Fe_2O_3/BC-CNFs复合负极材料的电化学性能研究  

Research on electrochemical performance of anchoring Fe_2O_3 nanoparticle on three-dimensional carbon nanofiber

作　　者：马小彪 陈思浩[3] 黎朝晖 胡林 Ma Xiaobiao;Chen Sihao;Li Zhaohui;Hu Lin(Fashion College, Shanghai University of Engineering Science, Shanghai 201620;Wasion Group Co. ,Ltd. ,Changsha 410205;College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620)

机构地区：[1]上海工程技术大学服装学院,上海201620 [2]威胜集团有限公司,长沙410205 [3]上海工程技术大学化学化工学院,上海201620

出　　处：《化工新型材料》2018年第4期131-134,共4页New Chemical Materials

摘　　要：通过水热法制备出纳米Fe_2O_3颗粒吸附于三维网状结构的碳纳米纤维(BC-CNFs)中,得到Fe_2O_3/BCCNFs。Fe_2O_3/BC-CNFs的电化学性能相对于聚集的Fe_2O_3纳米颗粒有很大的提高,表明在整个电极循环过程BCCNFs对与Fe_2O_3的机械稳定性和导电性以及防止纳米颗粒聚集起到关键性的作用,并且Fe_2O_3/BC-CNFs网状结构中存在大量的相互连接的多孔结构,有助于锂离子的快速分散和传递。以200mA/g的电流循环100次具有500mAh/g稳定的比容量,其较高的可逆容量和良好的倍率性能主要归因于三维网状多孔结构以及Fe_2O_3纳米颗粒在其内部纤维表面良好的分散性。Nano Fe2O3 was anchored on three-dimensional （3D） carbon nanofiber （CNFs） aerogels （Fe2O3/BC- CNFs） by hydrothermal route.The significant improved cycling performance of Fe2O3/BC-CNFs when compared to the bare Fe2O3 clearly indicated that the introduced BC-CNFs played a critical role in mechanically and electrically binding Fe2O3 nanoparticles together at the whole electrode scale, and also offering numerous interconnected voids in the porous Fe2O3/BC-CNFs hybrid which was favorable for the fast diffusion and transport of lithium ions. In addition to its excellent flexibility,a stable capacity of 500mAh/g for up to 100 cycles was also higher than most of carbon-Fe2O3 hybrids.The high reversible capacity and excellent rate capability were attributed to its 3D porous network structure with well-dispersed Fe2O3 nanoparticles on the surfaces of CNFs.

关 键 词：碳纳米纤维 细菌纤维素 复合材料 电化学性能 

分 类 号：O646.54[理学—物理化学] TB332[理学—化学]