双金属金属有机骨架材料的制备及性能研究进展  

Research Progress in Preparation Technology and Application of Bimetal Metal-Organic Frameworks Materials

作　　者：元宁 杜冰洁 贾晓霞[1] 杨江峰[1] 李晋平[1] YUAN Ning;DU Bingjie;JIA Xiaoxia;YANG Jiangfeng;LI Jinping(College of Chemistry and Chemical Engineering（Research Institute of Special Chemicals ）, Taiyuan University of Technology, Taiyuan 030024, Chin)

机构地区：[1]太原理工大学化学化工学院精细化工研究所,太原030024

出　　处：《应用化学》2018年第5期500-510,共11页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金项目(21676175)~~

摘　　要：金属有机骨架材料(MOFs)具有拓扑结构的多样性和丰富的比表面积,使其在催化和吸附领域具有潜在的应用价值。双金属MOFs具有两种金属中心,较之单金属MOFs具有更加多元的催化活性位点和吸附位点,因此吸附选择性、选择催化性以及结构稳定性等均得到了提升。本文就如何制备性能优异的双金属MOFs材料,以及这种材料的结构特点、性能提升和应用前景展开了概述。Metal-organic frameworks（ MOFs） have the diversity of topological structure and rich surface area,which make it have potential application value in the field of catalysis and adsorption. Because of the bimetallic MOFs have two metal centers,it has higher catalytic activity sites and adsorption sites than the single metal MOFs. So the selectivity of adsorption,catalytic activity,and stability of structure have all been improved. In this review, the synthesis methods, structure properties, performance improvement and application prospects of bimetallic MOFs are summarized.

关 键 词：金属有机骨架材料(MOFs) 双金属结构 一锅法 金属取代 

分 类 号：O641.4[理学—物理化学]