碳材料在染料敏化太阳能电池和钙钛矿太阳能电池对电极中的应用进展  

Novel Progress on Application of Carbon Materials as Counter Electrode in Dye-sensitized Solar Cells and Perovskite Solar Cells

作　　者：张晴[1] 黄其煜[1] ZHANG Qing;HUANG Qi yu(of Micro/Nano electronics,Shanghai University, Shanghai 200240, Chin)

机构地区：[1]上海交通大学微纳电子学系,上海200240

出　　处：《材料工程》2018年第5期56-63,共8页Journal of Materials Engineering

基　　金：上海市科学技术委员会资助课题(13ZR1420700)

摘　　要：染料敏化太阳能电池和钙钛矿太阳能电池是目前太阳能电池领域的研究热点,但这两种电池中使用的传统对电极材料,如Pt和Au等稀有且价格昂贵,不利于大规模量产。碳材料作为除Pt,Au等之外的另一种候选材料,其种类丰富且成本低廉,作为对电极应用在这两类电池中具有逐渐接近甚至超越传统电池的光电转换效率,表现出良好的应用前景。本文综述了作为两类电池对电极的碳材料具备的结构、性能及对电池光伏性能的影响,着重介绍各种形式的碳材料应用于对电极的最新研究进展,并指出现有研究存在的局限性与待解决的问题,讨论了碳材料对电极未来的研究方向。Dye sensitized solar cells （DSSCs） and perovskite solar cells （PSCs） are ＂the research focuses at present in ＂the field of solar ceils. However, ＂the commonly used counter electrodes （CEs） in ＂these ＂two solar ceils, such as Pt and Au, are rare and expensive, ＂they are not suitable for mass production. Low cost and abundant carbon based materials can substitute Pt and Au in DSSCs and PSCs as CEs, showing gradually approaching or even higher photoelectric conversion efficiency and suggesting a bright future. The structure and electrochemical properties of carbon based materials as well as ＂the photovoltaic performances as CEs were reviewed in ＂this paper. The recent advances achieved by car bon based CEs were highlighted, and ＂the limitations and unsettled were also pointed out, and finally, the possible directions for further problems in present researches research were discussed.

关 键 词：碳材料 对电极 染料敏化太阳能电池 钙钛矿太阳能电池 

分 类 号：TM914.4[电气工程—电力电子与电力传动]