有机磷-氮系协同阻燃剂的研究进展及其表征  

Research Progress and Characterization of Organic Phosphorus and Nitrogen Synergistic Flame Retardants

作　　者：罗星 谢德龙 梅毅 杨云艳 郑睿知 LUO Xing;XIE De-long;MEI Yi;YANG Yun-yan;ZHENG Rui-zhi(Facuhy of Chemical Engineering, Kunming University of Science and Technolog;The Hiher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province, Kunming University of Science and Technology, Kunming 650500, Chin)

机构地区：[1]昆明理工大学化学工程学院云南省高校磷化工重点实验室,云南昆明650500

出　　处：《塑料工业》2018年第4期20-25,94,共7页China Plastics Industry

基　　金：国家自然科学地区基金(21663015)

摘　　要：有机磷-氮协同阻燃剂是一类无卤、无毒、高效、环保的阻燃剂,阻燃元素磷和氮的增效作用使其具有优异的阻燃性能,成为了有机高分子材料重要的阻燃剂之一。概述了不同结构的有机磷-氮协同阻燃剂的研究进展,对不同阻燃基材性能进行了总结,对阻燃剂结构的红外光谱、核磁共振光谱等表征方法进行简单阐述,最后对有机磷-氮协同阻燃剂发展前景进行展望,指出多种提高磷-氮协同阻燃剂阻燃性能的途径。Organic phosphorus-nitrogen synergistic flame retardants had great advantages in terms of halogen-free, non-toxicity, high efficience and environmental protection. The excellent flame-retardant property was supposed to benefit from the synergistic effect of flame-retardant phosphorus and nitrogen elements. Therefore, organic phosphorus-nitrogen synergistic flame retardants were regarded as vital flame retardants. The different structure of flame retardants and the characterization of organic phosphons-nitrogen synergistic flame retardants were discussed. In addition, the development trends of the organic phosphorus- nitrogen synergistic flame retardants were prospected together with the important approaches of improving the phosphorus-nitrogen flame retardant properties.

关 键 词：磷-氮协同阻燃剂 笼状 9 10-二氢-9-氧杂-10-磷杂菲-10-氧化物型 磷腈型 链状 支化型 结构表征 

分 类 号：TQ314.248[化学工程—高聚物工业]