氨基金属酞菁/磷钼钒杂多酸荷移配合物的合成与表征  

Synthesis and characterization amino metal phthalocyanine/phospho molybdate vanadium heteropoly acid charge transfer complex

作　　者：尹彦冰[1] 张闻天子 张迅 王宇萌 YIN Yan-bing;ZHANG Wen-tianzi;ZHANG Xun;WANG Yu-meng(School of Chemistry and Chemical Engineering,Qiqihar University,Qiqihar 161006,China)

机构地区：[1]齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔161006

出　　处：《高师理科学刊》2018年第4期27-30,共4页Journal of Science of Teachers＇College and University

基　　金：博士后研究人员落户黑龙江科研启动基金项目(2012)

摘　　要：以四氨基铜酞菁与Keggin型磷钼钒杂多酸为原料,N,N-二甲基甲酰胺为溶剂,在35℃下通过离子交换法合成了一种新型有机/无机复合配合物——氨基铜酞菁/磷钼钒杂多酸荷移配合物.对这种产物进行了紫外-可见光谱、红外光谱的表征.结果表明,这种新型配合物中仍然保留着酞菁的环状结构和杂多酸的笼状结构,紫外光谱和红外光谱中特征吸收峰出现一定程度的红移,说明两者之间是以化学键的形式发生了键合.A novel organic/inorganic complex——amino copper phthalocyanine/phospho molybdate vanadium heteropoly acid charge transfer complex was synthesized by ion exchange at 35 ℃ while tetraamino copper phthalocyanine and Keggin-type/phospho molybdate vanadium heteropoly acid were selected as raw materials,N,N-dimethylformamide as a solvent.The structures were characterized by UV-Vis spectra and FTIR spectra.The results showed that,the cyclic structure of the phthalocyanine and the cage structure of the heteropolyacid were remained in the novel complex,a certain degree red shift of the characteristic absorption peak were found in the UV-Vis and IR spectra,which indicates that the chemical bond is formed between the two.

关 键 词：氨基酞菁 磷钼钒杂多酸 荷移配合物 

分 类 号：O625[理学—有机化学]