水蒸气活化法制备长柄扁桃壳基介孔活性炭的研究  

Preparation of Mesoporous-activated Carbon from Amygdalus Pedunculata Shell by Steam Activation

作　　者：李少妮 孙康[1] 申烨华[2] 李聪[2] 李继辉 LI Shaoni;SUN Kang;SHEN Yehua;LI Cong;LI Jlhui(Institute of Chemical Industry of Forest Products,CAF;National Engineering Lab.For Biomass Chemical Utilizatio;Key and Open Lab.of Forest Chemical Engineering,SF;Key Lab.of Biomass Energy- and Material,Jiangsu Province,Nanjing 210042,China;2.Key Lab.of Synthetic and Natural Functional Molecule Chemistry of Ministry of Educatio;College of Chemistry and Materials Science,Northwest Universit;The Amygdalus Pedunculata Engineering Research Center of the State Forestry- Administration of the PR;Key Lab.of Yulin Desert Plants Resource;Shaanxi Alcohol Ether and Biomass Engineering Research Center,Xi＇an 710069,China)

机构地区：[1]中国林业科学研究院林产化学工业研究所生物质化学利用国家工程实验室国家林业局林产化学工程重点开放性实验室江苏省生物质能源与材料重点实验室,江苏南京210042 [2]合成与天然功能分子化学教育部重点实验室西北大学化学与材料科学学院国家林业局长柄扁桃工程技术研究中心榆林市沙漠植物资源重点实验室陕西省醇醚及生物质能源工程研究中心,陕西西安710069

出　　处：《生物质化学工程》2018年第3期9-15,共7页Biomass Chemical Engineering

基　　金：国家自然科学基金面上项目(31770629)

摘　　要：以沙漠治理树种长柄扁桃的种壳为原料,采用水蒸气活化法制得了介孔发达的活性炭,并研究了炭化温度、活化温度、活化时间、水蒸气用量对活性炭吸附性能及产率的影响。结果表明:在炭化温度600℃、活化温度850℃、活化时间60 min、水蒸气与炭化料的质量比为6∶1的最佳工艺条件下,制得活性炭样品的产率为12%,碘吸附值和亚甲基蓝吸附值分别达到1 175和315 mg/g,介孔率为60.9%,比表面积为1 127 m^2/g,平均孔径2.6 nm,在吸附平衡时间为24 h时,活性炭对水溶液中头孢氨苄的吸附量高达245 mg/g,优于相同条件下制得的椰壳和核桃壳活性炭的吸附能力。Activated carbon with developed mesopore were prepared from Amygdalus pedunculata shell by steam activation at different technology condition. The effects of carbonization temperature,activation temperature,activation time and steam dosage on the adsorption properties and yield of resulting activated carbon were analyzed. The results showed that the optimal activated carbon was obtained at carbonization temperature 600 ℃,activation temperature 850 ℃,activation time 60 min and steam/carbide weight ratio 6∶1,whose yield,iodine value,methylene blue value,mesopore ratio,BET surface area and average pore size were 12 %,1 175 mg/g,315 mg/g,60. 9 %,1 127 m^2/g and 2. 6 nm,respectively. Besides,the results of adsorption experiment indicated that the activated carbon prepared at the optimal conditions was promising absorbent for cephalexin,the equilibrium adsorption capacity could reach 245 mg/g after 24 h,which was higher than that of coconut shell activated carbon and walnut shell activated carbon prepared under the same conditions.

关 键 词：长柄扁桃壳 水蒸气活化 介孔活性炭 头孢氨苄 

分 类 号：TQ424[化学工程] TQ35