The development of MOFs-based nanomaterials in heterogeneous organocatalysis  

作　　者：Xiaomei Liu Bing Tang Jilan Long Wei Zhang Xiaohong Liu Zakaria Mirza 

机构地区：[1]Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, Institute of Applied Chemistry, College of Chemistry and Chemical Engineering, China West Normal University [2]Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences [3]Department of Laboratory Medicine, Southwest Hospital, Third Military Medical University (Army Medical University)

出　　处：《Science Bulletin》2018年第8期502-524,共23页科学通报（英文版）

基　　金：supported by the National Natural Science Foundation of China(21706217);Scientific Research Fund of Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province(CSPC2015-1-2);Scientific Research Fund of China West normal University(15E009);Scientific Research Fund of Sichuan Provincial Education Department(17AZ0382,17TD0036);the Meritocracy Research Funds of China West normal University(17YC029);the Fundamental Research Funds of China West normal University(17C035);Scientific Research Fund of Science&Technology of Sichuan Province(2017JY0015);Youth Innovation Promotion Association of CAS(2015316);the National High Technology Research and Development Program of China(2015AA021107)

摘　　要：Metal-organic framework(MOF) is a class of inorganic-organic hybrid material assembled periodically with metal ions and organic ligands. MOFs have always been the focuses in a variety of frontier fields owing to the advantageous properties, such as large BET surface areas, tunable porosity and easyfunctionalized surface structure. Among the various application areas, catalysis is one of the earliest application fields of MOFs-based materials and is one of the fastest-growing topics. In this review, the main roles of MOFs in heterogeneous organocatalysis have been systematically summarized, including used as support materials(or hosts), independent catalysts, and sacrificial templates. Moreover, the application prospects of MOFs in photocatalysis and electrocatalysis frontiers were also mentioned.Finally, the key issues that should be conquered in future were briefly sketched in the final parts of each item. We hope our perspectives could be beneficial for the readers to better understand these topics and issues, and could also provide a direction for the future exploration of some novel types of MOFs-based nanocatalysts with stable structures and functions for heterogeneous catalysis.Metal-organic framework （MOF） is a class of inorganic-organic hybrid material assembled periodically with metal ions and organic ligands. MOFs have always been the focuses in a variety of frontier fields owing to the advantageous properties, such as large BET surface areas, tunable porosity and easy- functionalized surface structure. Among the various application areas, catalysis is one of the earliest application fields of MOFs-based materials and is one of the fastest-growing topics. In this review, the main roles of MOFs in heterogeneous organocatalysis have been systematically summarized, including used as support materials （or hosts）, independent catalysts, and sacrificial templates. Moreover, the application prospects of MOFs in photocatalysis and electrocatalysis frontiers were also mentioned. Finally, the key issues that should be conquered in future were briefly sketched in the final parts of each item. We hope our perspectives could be beneficial for the readers to better understand these topics and issues, and could also provide a direction for the future exploration of some novel types of MOFs-based nanocatalysts with stable structures and functions for heterogeneous catalysis.

关 键 词：Metal-organic framework Heterogeneous organocatalysis Support materials Independent catalysts Sacrificial templates Photocatalysis and electrocatalysis 

分 类 号：O643.36[理学—物理化学] TP393[理学—化学]