轻质可压缩壳聚糖/石墨烯复合气凝胶的制备与性能  

Lightweight and Compressible Chitosan/Graphene Composite Aerogels

作　　者：魏燕红[1] 孙芙蓉[1] 杨季雨 何屹[1] 高元吉 吴锦荣[2] 赵丽娟[1] Yanhong Wei;Furong Sun;Jiyu Yang;Yi He;Yuanji Gao;Jinrong Wu;Liiuan Zhao(College of Chemistry and Material Science, Sichuan Normal University, Chengdu 610068, China;College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China)

机构地区：[1]四川师范大学化学与材料科学学院,四川成都610068 [2]四川大学高分子科学与工程学院,四川成都610065

出　　处：《高分子材料科学与工程》2018年第5期149-154,共6页Polymer Materials Science & Engineering

基　　金：国家自然科学基金资助项目(51303116);四川师范大学开放实验项目

摘　　要：以石墨烯气凝胶(GA)为骨架,向其浇注壳聚糖(CS)醋酸溶液制备出多重网络结构的壳聚糖/石墨烯复合气凝胶(CGA),并探究了气凝胶的微观结构与性能的关系。采用扫描电镜、红外光谱、比表面积分析、热常数分析以及压缩性能测试等方法详细表征了材料的结构和性能。研究发现,杂化气凝胶丰富发达的孔洞结构赋予了材料轻质低密度的特性;多重网络结构的构筑,使材料具有良好的回弹性;CS与GA在界面上交联,使杂化气凝胶的压缩强度由10.02 kPa提高到99.83 kPa,弹性模量由19.75 kPa增加至244.66 kPa。这种有机-无机多重网络结构的设计,提高了GA的可压缩性,解决了GA压缩易破碎的问题。In this work,a kind of triple network structure aerogel was fabricated from graphene oxide（ GO） and chitosan（ CS） by template method,meanwhile,the relationship between microstructure and mechanical properties was studied by SEM,FT-IR,BET,thermal constant analyzer and universal testing machines. It is shown that the first network serves as sacrificial bonds and dissipates energy upon deformation,then the second network increases the toughness of composite aerogels,and the third network is to store strain energy. These multiple networks endow the hybrid aerogels with high compressible property and flexibility. Moreover,the composite aerogels are lightweight with low apparent density（ 19. 76 mg/cm^3）,due to its highly porous. The organic-inorganic multiple networks provide a new insight in designing lightweight and compressible aerogels.

关 键 词：石墨烯 壳聚糖 气凝胶 轻质 可压缩 

分 类 号：TB332[一般工业技术—材料科学与工程]