ZrO_2:Eu^(3+),Y^(3+)转光膜的制备及其在蓝光危害防护中的应用  

Preparation of ZrO_2:Eu^(3+),Y^(3+) Light Conversion Film and Its Application in Protection Against Blue Light Hazard

作　　者：莫忠 梁立容 Mo Zhong;Liang Lirong(School of Biomedical Engineering, College of Xinhua, Sun Yat-Sen University, Guangzhou, Guangdong 510520, China;School of Information Science,College of Xinhua,Sun Yat-Sen University,Guangzhou,Guangdong 510520,China)

机构地区：[1]中山大学新华学院生物医学工程学院,广东广州510520 [2]中山大学新华学院信息科学学院,广东广州510520

出　　处：《激光与光电子学进展》2018年第5期438-442,共5页Laser & Optoelectronics Progress

基　　金：国家自然科学基金面上项目(61672546);中山大学新华学院科研基金(2017YB004)

摘　　要：采用化学溶液沉积法,在石英玻璃上制备了ZrO_2:Eu^(3+),Y^(3+)(Eu-YSZ)转光膜,研究了Eu^(3+)、Y^(3+)掺杂浓度对薄膜的晶体结构、表面形貌和光学性能的影响。在波长为396nm的紫外光和波长为466nm的蓝光照射下,EuYSZ薄膜可发射出发光中心在593nm和609nm附近的红光带,这归因于Eu^(3+)离子的能级跃迁,且薄膜在可见光区间具有较高的透过率。研究表明,Eu-YSZ转光膜有利于减少短波蓝光对人眼视网膜造成的伤害。The ZrO2 ：Eu^3＋, Y^3＋ （Eu-YSZ） light conversion films are prepared on the fused silica substrates by using the chemical solution deposition method. The effects of Eu^3＋ and Y^3＋ doping concentrations on crystal structure, surface morphology and optical properties of thin films are investigated. Under the irradiation of ultraviolet light with a wavelength of 396 nm and blue light with a wavelength of 466 nm, the Eu-YSZ thin films show bright red emission bands centered at 593 nm and 609 nm, which are attributed to the energy level transitions of Eu^3＋ ions. In addition, the thin films show a relatively high visible light transmittance. The study suggests that the Eu-YSZ light conversion films are beneficial to reduce the damage of short wave blue light to the retina of human eyes.

关 键 词：薄膜 ZrO2:Eu^3+ Y^3+ 转光膜 蓝光危害 化学溶液沉积 

分 类 号：O484[理学—固体物理]