新型大环超分子化学:从杂杯芳烃到冠芳烃——纪念黄志镗先生诞辰90周年  

Macrocyclic and Supramolecular Chemistry: From Heteracalixaromatics to Coronarenes——In Memory of Professor Zhi-Tang Huang

作　　者：王梅祥[1] MeiXiang Wang(MOE Key Laboratory of Bioorganic Phosphorous Chemistry and Chemical Biology, Department of Chemistry, Tsinghua University, Beijing 100084, China)

机构地区：[1]清华大学化学系生命有机磷化学及化学生物学教育部重点实验室,北京100084

出　　处：《化学进展》2018年第5期463-475,共13页Progress in Chemistry

基　　金：国家自然科学基金项目(No.21732004;21572111;91427301)资助~~

摘　　要：本文介绍了杂杯芳烃和冠芳烃的研究起源,总结了杂杯芳烃和冠芳烃的设计与合成、构象和大环空腔结构特征,展示了杂杯芳烃和冠芳烃的分子识别和组装性质,概述了杂杯芳烃和冠芳烃在功能材料的制备中的应用,展望了大环超分子化学未来的发展方向。Research history of heteracalixaromatics and coronarenes are introduced herein. The design and synthesis of heteracalixaromatics and coronarenes are summarized followed by the description of the macrocyclic conformation and cavity structures. Molecular recognition towards cations, anions and neutral guest species and property of molecular assembly of these macrocyclic hosts are presented. Applications of heteracalixaromatics and coronarenes in the fabrication of functional materials are also demonstrated briefly. The future perspectives of heteracalixaromatics and coronarenes in macrocyclic and supramolecular chemistry are discussed at last.

关 键 词：杂杯芳烃 冠芳烃 大环化学 分子识别 超分子化学 

分 类 号：O641.3[理学—物理化学] O621.3[理学—化学]