CO_2:羧基化反应的C1合成子  

CO_2: C_1 Synthon in Carboxylation Reactions

作　　者：张宇 岑竞鹤 熊文芳 戚朝荣 江焕峰 Yu Zhang;Jinghe Cen;Wenfang Xiong;Chaorong Qi;Huanfeng Jiang(Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China)

机构地区：[1]华南理工大学化学与化工学院广东省功能分子工程重点实验室,广州510640

出　　处：《化学进展》2018年第5期547-563,共17页Progress in Chemistry

基　　金：国家自然科学基金项目(No.2016YFA0602900)资助~~

摘　　要：基于资源与环境的考虑,以二氧化碳为原料的有机合成研究近年来日益受到科学家们的关注,其中以二氧化碳为C1合成子参与的过渡金属催化羧基化反应由于可有效构建各种羧酸类化合物及其衍生物,是二氧化碳利用和实现碳循环的理想途径之一。本文综述了催化活化二氧化碳与亲电试剂、烃类C—H键化合物、亲核试剂等通过构建新碳-碳键实现羧基化反应的最新研究进展。Recently organic synthesis using carbon dioxide as the raw material has attracted considerable attention from scientists because of the resourceful and environmental factors. Especially, transition metal-catalyzed carboxylation reaction is an efficient method to construct carboxylic acids and their derivatives, which is regarded as one of ideal strategies for carbon dioxide utilization and carbon recycle. The recent advances of carboxylation reaction of CO2 with various substrates （electrophiles, hydrocarbons, nucleophiles） are reviewed herein.

关 键 词：二氧化碳 C1合成子 羧基化 碳-碳成键 过渡金属催化 

分 类 号：O621.3[理学—有机化学] O621.256.4[理学—化学]