功能化石墨烯/溶聚丁苯橡胶复合材料的物理和电学性能研究  

Physical and Electrical Properties of Functionalized Graphene/Solution Polymerized Styrene-Butadiene Rubber Composite

作　　者：郑龙 黎妍 许宗超 张立群[1] 刘力[1,2] 温世鹏[1] ZHENG Long;LI Yan;XU Zongchao;ZHANG Liqun;LIU Li;WEN Shipeng(Beijing University of Chemical Technology,Beijing 100029, China)

机构地区：[1]北京化工大学北京市先进弹性体工程技术研究中心,北京100029 [2]北京化工大学化工资源有效利用国家重点实验室,北京100029

出　　处：《橡胶工业》2018年第6期612-618,共7页China Rubber Industry

基　　金：国家"973"计划项目[2015CB654700(2015CB674705)];国家自然科学基金资助项目(51573007;51503004);中央高校基本科研业务费资助项目(JD1513/ZD1503);北京市科技计划课题(Z171100002217033)

摘　　要：采用十八烷基胺对氧化石墨烯进行表面改性,用硼氢化钠对其进行还原,得到功能化石墨烯(ARG),并通过溶液复合法制备ARG/溶聚丁苯橡胶(SSBR)复合材料,对其性能进行研究。结果表明:ARG在SSBR基体中的分散较为均匀;加入ARG的复合材料的物理性能明显提高;当ARG用量为3份时,复合材料达到了导电渗流阈值;当ARG用量为12份时,复合材料的导电性能最佳;随着ARG用量的增大,复合材料的介电常数增大。Functionalized graphene（ARG）was obtained by surface modification of graphene oxide using octadecylamine and then reduction by sodium borohydride. Subsequently,the ARG/solution polymerized styrene-butadiene rubber（SSBR）composite was prepared through solution compounding method,and its properties were investigated. The results showed that,ARG was dispersed well in SSBR matrix. The physical properties of the composite filled with AGR were obviously improved. The conductive percolation threshold in the composite appeared at 3 phr ARG. When the addition level of ARG was 12 phr,the conductivity of the composite were the best. As the addition level of ARG increased,the dielectric constant of the composite increased.

关 键 词：十八烷基胺 氧化石墨烯 功能化石墨烯 溶聚丁苯橡胶 导电性能 介电性能 

分 类 号：TQ330.385[化学工程—橡胶工业] TQ332