Fuel properties and emission characteristics of biodiesel produced from unused algae grown in India  

作　　者：Rachan Karmakar Krishnendu Kundu Anita Rajor 

机构地区：[1]School of Energy and Environment, Thapar University [2]Department of Biofuel, CSIR CMERI CoEFM

出　　处：《Petroleum Science》2018年第2期385-395,共11页石油科学（英文版）

摘　　要：The high price of different biodiesels and the need for many of their raw ingredients as food materials are the main constraints to be overcome when seeking the best potential alternative fuels to petro-diesel. Apart from that, some properties like high density, viscosity and acid value along with low cloud and pour points preclude their use in com- pression ignition （CI） engines as these properties can cause serious damage to the parts of the engine and reduce engine life. In this experiment, biodiesel was produced from the oil of unused algae by a two-step ＇acid esterification followed by transesterification＇ procedure. Taguchi＇s method was applied to design the experiment, and a L25 orthogonal array was prepared to optimize the biodiesel production procedure. The optimized conditions for transesterification were： methanol to oil molar ratio of 6：1, catalyst （KOH） concentration of 2.5 wt%, reaction time of 90 min and reaction temperature of 50 ~C, achieving a biodiesel production of 89.7% with free fatty acid content of 0.25%. It was found that the CI engine emitted less CO, CO2 and hydrocarbon and higher NOx using algal biodiesel than that using petro-diesel. All properties of the algal biodiesel were within the limit of ASTM standards.The high price of different biodiesels and the need for many of their raw ingredients as food materials are the main constraints to be overcome when seeking the best potential alternative fuels to petro-diesel. Apart from that, some properties like high density, viscosity and acid value along with low cloud and pour points preclude their use in com- pression ignition （CI） engines as these properties can cause serious damage to the parts of the engine and reduce engine life. In this experiment, biodiesel was produced from the oil of unused algae by a two-step ＇acid esterification followed by transesterification＇ procedure. Taguchi＇s method was applied to design the experiment, and a L25 orthogonal array was prepared to optimize the biodiesel production procedure. The optimized conditions for transesterification were： methanol to oil molar ratio of 6：1, catalyst （KOH） concentration of 2.5 wt%, reaction time of 90 min and reaction temperature of 50 ~C, achieving a biodiesel production of 89.7% with free fatty acid content of 0.25%. It was found that the CI engine emitted less CO, CO2 and hydrocarbon and higher NOx using algal biodiesel than that using petro-diesel. All properties of the algal biodiesel were within the limit of ASTM standards.

关 键 词：ALGAE BIODIESEL Fuel characterization EMISSION 

分 类 号：TE667[石油与天然气工程—油气加工工程]