Effect of Constituent Core-sizes on Microstructure and Dielectric Properties of BaTiO_3@(0.6BaTiO_3-0.4BiAlO_3) Core-Shell Material  

作　　者：APPIAH Millicent 郝华 CHEN Wenjin CHEN Cheng YAO Zhonghua CAO Minghe LIU Hanxing 

机构地区：[1]State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Material Science and Engineering,Wuhan University of Technology [2]International School of Materials Science and Engineering, Wuhan University of Technology

出　　处：《Journal of Wuhan University of Technology(Materials Science)》2018年第3期589-597,共9页武汉理工大学学报（材料科学英文版）

基　　金：Funded by NSFC-Guangdong Joint Funds of the Natural Science Foundation of China(No.U1601209);the National Key Basic Research Program of China(973 Program)(No.2015CB654601);National Natural Science Foundation of China(No.51372191)

摘　　要：The fundamental characteristics of varied initial core-sizes of Ba Ti O3（BT） and its influential role on the morphology and dielectric properties of Ba Ti O3@0.6 Ba Ti O3-0.4 Bi Al O3（BT@0.6 BT-0.4 BA） ceramic samples were studied. Alkoxide sol-precipitation method was adopted as revised chemical route to synthesize the constituent ＂core＂ BT powders in a dispersed phase, whereas the distinctive initial nano-sized particles were affected by the pre-calcination temperatures（600-900 ℃）.The microstructure of the uncoated BT ceramics revealed an exaggerated grain growth with an optimized dielectric constant（ε（max） 〉9 000） whilst the coated ceramics behaved otherwise（grain growth inhibited） when sintered at an elevated temperature. Regardless of the previously studied solubility limit（about 0.1%） of BT-BA samples, BT@0.6 BT-0.4 BA maintained a maximum dielectric constant（ε（max）） ranging from 1 592 to 1 708 and tan δ less than 2% under a unit mole ratio at room temperature. In view of all these analyses, the initial nanometer sizes of the as-prepared BT-core powders combined with the increase effect of cation substitutions of Bi^（3＋） and Al^（3＋） in the shell content, induced the diffuse transition phase of BT@0.6 BT-0.4 BA composition.The fundamental characteristics of varied initial core-sizes of Ba Ti O3（BT） and its influential role on the morphology and dielectric properties of Ba Ti O3@0.6 Ba Ti O3-0.4 Bi Al O3（BT@0.6 BT-0.4 BA） ceramic samples were studied. Alkoxide sol-precipitation method was adopted as revised chemical route to synthesize the constituent ＂core＂ BT powders in a dispersed phase, whereas the distinctive initial nano-sized particles were affected by the pre-calcination temperatures（600-900 ℃）.The microstructure of the uncoated BT ceramics revealed an exaggerated grain growth with an optimized dielectric constant（ε（max） 〉9 000） whilst the coated ceramics behaved otherwise（grain growth inhibited） when sintered at an elevated temperature. Regardless of the previously studied solubility limit（about 0.1%） of BT-BA samples, BT@0.6 BT-0.4 BA maintained a maximum dielectric constant（ε（max）） ranging from 1 592 to 1 708 and tan δ less than 2% under a unit mole ratio at room temperature. In view of all these analyses, the initial nanometer sizes of the as-prepared BT-core powders combined with the increase effect of cation substitutions of Bi^（3＋） and Al^（3＋） in the shell content, induced the diffuse transition phase of BT@0.6 BT-0.4 BA composition.

关 键 词：MLCCs core-shell Alkoxide sol-precipitation relaxor grain boundary segregation 

分 类 号：TQ174.1[化学工程—陶瓷工业]