α-蒎烯催化异构化制莰烯的研究进展  

Research progress in α-pinene catalytic isomerization to camphene

作　　者：丁雨晴 蒋丽红[1] 王亚明[1] DING Yuqing;JIANG Lihong;WANG Yarning(Faculty of Chemical Engineering ,Kunming University of Science and Technology ,Kunming 650500, Chin)

机构地区：[1]昆明理工大学化学工程学院,云南昆明650500

出　　处：《化工科技》2018年第3期70-75,共6页Science & Technology in Chemical Industry

基　　金：国家自然科学基金项目(21266012);国家自然科学基金联合基金重点支持项目(U1202265)

摘　　要：α-蒎烯是一种重要的可再生资源,因其特殊的单环双键结构而具有较高的化学活性,在医学及农药领域有着广泛的应用。介绍了近几年α-蒎烯异构化的反应机理及产物莰烯的发展状况,详细介绍了目前研究的几种催化剂,如固体超强酸、沸石分子筛、杂多酸及其它催化剂,系统地介绍了酸催化剂,同时对表面酸位点与催化性能间的关系进行了初探与总结,分析并展望了α-蒎烯及莰烯的未来发展前景。α-Pinene is an important renewable resource.The high chemical activity ofα-pinene is ascribed to its special single ring double bond structure,which has a wide range of applications in the field of medicine and pesticides.This article reviewed the development of reaction mechanism and product of camphene inα-pinene isomerization reaction in recent years.We summarized some typical coordinatively catalysts in recent years,such as solid super acid,zeolite molecular sieves,heteropoly acid and so on,which are suitable forα-pinene isomerization.The acid catalysis and expand their application in the future were systematically introduced.At the same time,this paper also pointed out that surface acid sites plays an important role in the catalytic performance of the catalysts,and its future research directions are analyzed and prospected.

关 键 词：Α-蒎烯 异构化反应 反应机理 催化剂 莰烯 

分 类 号：O613.32[理学—无机化学]