紫外红外强吸收钠硼硅玻璃的制备与研究  

Preparation and Research of Uv-infrared Strong Absorption Sodium Borosilicate Glass

作　　者：潘国治 张振华 符有杰 赵会峰 姜宏 PAN Guo- zhi;ZHANG Zhen- hua;FU You- jieh;ZHAO Hui- feng;JIANG Hong(AVIC（Hainan）Special Glass Technology Co.,L td.,Chengmai 571924,China;Key Laboratory of Special Glass,Chengmai 571924,China;A VIC（Guangdong）Special Glass Technology Co.,Ltd.,Huizhou 516000,China;Key Laboratory of Special Glass in Hainan Province,Hainan University,Haikou 570228,China)

机构地区：[1]海南中航特玻科技有限公司,澄迈571924 [2]特种玻璃国家重点实验室,澄迈571924 [3]广东中航特种玻璃技术有限公司,惠州516000 [4]海南大学,海南省特种玻璃重点实验室,海口570228

出　　处：《硅酸盐通报》2018年第5期1753-1757,1764,共6页Bulletin of the Chinese Ceramic Society

基　　金：中航工业通飞科技发展研究项目(TFKY2015002)

摘　　要：采用高温熔融法,在钠硼硅玻璃体系中掺入稀土与金属氧化物制备了紫外红外强吸收的节能环保玻璃,并研究了不同稀土与金属氧化物掺杂量对玻璃光学、热学及结构等性能的影响。研究表明:在保证一定可见光透过率的前提下,通过调节稀土与金属氧化物的量可提高紫外红外吸收:随着CeO_2和TiO_2共掺杂量增加,玻璃的紫外透过率随着掺杂量增加而明显下降,而近红外透过率却上升;随着Fe_2O_3和SnO_2共掺杂量增加,玻璃的紫外、可见光和近红外透过率随着掺杂量增加而明显下降;当CeO_2、TiO_2、Fe_2O_3和SnO_2掺杂质量百分数分别约为0.6%、1%、0.6%和1%时,紫外平均透过率Tuv≤5%,近红外平均透过率Tir≤20%;同时,此钠硼硅玻璃热学和机械性能等较好于普通钠钙硅玻璃。Using high temperature melting method,in the system of sodium borosilicate glass doped with rare earth and metal oxide was prepared by uv-infrared strong absorption of energy conservation and environmental protection glass,and researched the different amount of rare earth and metal oxide doped glass optical,thermal and structure,etc. The research shows that,under the precondition of ensuring certain visible light transmittance,the uv-infrared absorption can be enhanced by regulating the amount of rare earth and metal oxides. With the increase of total doping of CeO2 and TiO2,the ultraviolettransmittance of glass decreased significantly with the increase of doping, while the near-infrared transmittance increased. With the increase of the total doping of Fe2O3 and SnO2,the ultraviolet-visible and near-infrared transmittance of glass decreased significantly with the increase of doping. When the quality percentages of CeO2,TiO2,Fe2O3 and SnO2 were about 0. 6%,1%,0. 6% and 1% respectively,the average transmittance of Tuv was less than 5%,and the average transmittance of Tir was less than 20%. At the same time,this sodium borosilicate glass pyrology and mechanical propertiesare better than normal sodium calcium silicate glass.

关 键 词：钠硼硅玻璃 本体掺杂 紫外吸收 红外吸收 节能环保 

分 类 号：TQ171[化学工程—玻璃工业]