我国离子交换与吸附树脂的发展历程回顾与展望  

Advance in Ion Exchange and Adsorption Resins in China

作　　者：张全兴[1] 张政朴[2] 李爱民[1] 潘丙才[1] 张孝林[1] Quan-xing Zhang;Zheng-pu Zhang;Ai-min Li;Bing-cai Pan;Xiao-lin Zhang(School of the Environment,National Engineering Research Center for Organic Pollution Control and Resource,Nanjing University,Nanjing 210023;Key Laboratory of Functional Polymer Materials of Ministry of Education,Institute of Polymer Chemistry,Nankai University,Tianjin 300071)

机构地区：[1]南京大学环境学院有机毒物污染控制与资源化国家工程技术研究中心,南京210023 [2]南开大学高分子化学研究所吸附分离功能高分子材料教育部重点实验室,天津300071

出　　处：《高分子学报》2018年第7期814-828,共15页Acta Polymerica Sinica

摘　　要：1949年以来,我国离子交换与吸附树脂领域在一代代科研工作者的不懈努力下取得了飞速发展,先后发展了凝胶树脂、大孔树脂、超高交联树脂、复合功能树脂及树脂基复合吸附剂等五代树脂,广泛应用于国防工业、医药卫生、精细化工、湿法冶金以及环境保护等领域,在我国不同发展时期均做出了突出贡献.本文总结了半个多世纪以来我国离子交换与吸附树脂领域发展的主要历程,重点回顾了以"中国离子交换树脂之父"何炳林先生为代表的离子交换与吸附事业先驱的历史贡献,并对离子交换与吸附树脂近年来的最新发展动向与成果进行简要介绍.Since 1949, China has been witnessing a rapid development in ion exchange and adsorption technology. Up to date, at least five generations of polymeric resins have been developed, including gel-type resin,macroporous resin, hyper-cross-linked resin, bifunctional resin and resin-based composite adsorbent. These resinbased materials have been widely utilized in various industries, including military defense, medical and health,fine chemicals, hydrometallurgy, environmental protection, making considerable contributions to the modernization of China. In brief, gel-type resin, characterized by non-porous nature, was first developed for uranium extraction and later expanded to other fields such as water softening. Due to abundant porous structure,macroporous resin exhibited faster ion exchange rate and higher mechanical strength over the gel-type one. A variety of macroporous adsorption resins were developed and widely utilized in separation and/or purification in the industries of food, chemicals, rare elements, drugs, toxins, and environmental remediation. Hyper-cross-linked resin was mainly prepared via Friedel-Crafts reaction, possessing ultra-high specific surface area（usually high than 800 m2/g） and abundant microporous structure. Hyper-cross-linked resins have been successfully applied for hemoperfusion purpose, representing one of the most promising adsorbents for organic pollutants in chemical industry effluents. Bifunctional resins were designed for adsorptive removal of highly water-soluble organic pollutants from industrial effluents, because they could offer multiple interactions with target pollutants such as π-π interaction, electrostatic attraction, hydrophobic interaction and hydrogen bonds. In the past decade, resin-based composite adsorbents, including resin-supported nanocomposite and magnetic resin, were obtained by integrating resin hosts with inorganic（nano） particles for advanced（waste） water treatment. The present review summarizes the development of ion exchange and adsorption re

关 键 词：离子交换与吸附树脂 凝胶树脂 大孔树脂 超高交联树脂 复合功能树脂 树脂基复合吸附剂 

分 类 号：TQ425.23[化学工程]