卟啉衍生物及其高分子材料  

Porphyrin-based Derivatives and Polymeric Materials

作　　者：张佳玮 马志远 赵传壮[3] 袁金颖[4] 朱晓夏[2] Jia-wei Zhang;Zhi-yuan Ma;Chuan-zhuang Zhao;Jin-ying Yuan;Xiao-xia Zhu(Ningbo Institute of Material Technology and Engineering,Chinese Academia of Sciences,Ningbo 315201;Department of Chemistry,Universite de Montreal,Montreal,QC,H3C3JT,Canada;College of Material Science and Chemical Engineering,Ningbo University,Ningbo 315211;Department of Chemistry,Tsinghua University,Beijing 100084)

机构地区：[1]中国科学院宁波材料工程与技术研究所,宁波315201 [2]蒙特利尔大学化学系蒙特利尔H3C3J7 [3]宁波大学材料科学与化学工程学院,宁波315211 [4]清华大学化学系,北京100084

出　　处：《高分子学报》2018年第7期864-877,共14页Acta Polymerica Sinica

基　　金：国家自然科学基金(基金号21604044); 国家留学基金委(基金号201708330059)资助项目

摘　　要：卟啉是一类由4个吡咯环通过次甲基相连而形成的共轭大环化合物.卟啉及其衍生物广泛存在于生物体内,参与催化、氧的输运和能量转移等重要生理过程.因其独特的生理功能和物理化学特性,卟啉衍生物及其高分子材料的制备和合成引起了广泛关注.本文介绍了卟啉及其衍生物在生命系统中的功能及其合成方法,回顾了含卟啉的高分子材料和超分子组装体的设计和制备方法,总结了近年来基于卟啉的高分子和超分子功能材料的研究动态.Porphyrins are naturally occurring macrocyclic compounds containing four pyrroles connected through four methine carbons at their α-positions. Porphyrins and their derivatives are widely found in biological systems and they engage in many essential processes that sustain living systems, such as enzyme catalysis, oxygen transportation and photosynthesis. The unique biological functions and physiochemical properties of porphyrin and its derivatives have made them interesting candidates in the preparation of functional materials for various applications. The recent progress on the synthesis and application of porphyrin derivatives and particularly the related macromolecular and supramolecular structures, is summarized in this review. Following a brief introduction on porphyrin and its derivatives in nature and on the binding and adsorption studies on porphyrinrelated bile pigments such as bilirubin, the strategies for the preparation of porphyrin-based polymers are reviewed, including the covalent polymerization and supramolecular self-assembly of linear polymers based on porphyrin, as well as two-and three-dimensional porphyrin assemblies and frameworks. The applications of porphyrin-based polymers and supramolecular-structures are also covered, which include： artificial enzymes,photo-dynamic therapy, chemical sensors, light-energy harvesting and medical imaging. These versatile functions are a synergetic result of porphyrin and its conjunct polymers： the porphyrin has unique photo-physical properties,and the polymers manifested porphyrin moieties stable and switchable chemical environment. Despite the progress having been made, the great potential as functional materials of porphyrin and its derivatives has not been fully exploited. In the future, tailoring the molecular topology of porphyrins-based polymer is believed to be an effective strategy of obtaining functional materials with controlled self-assembly structure. Constructing higherordered structure with supramolecular self-assembled porphyrin derivati

关 键 词：卟啉 卟啉衍生物 功能高分子 

分 类 号：O626[理学—有机化学] O633.5[理学—化学]