正丁醇与氯化氢反应生成氯丁烷动力学研究  

Kinetics of n-butyl chloride synthesis

作　　者：余德芳[1] 李军[1] 金央[1] 陈明 张宇强[1] YU De-fang;LI Jun;JIN Yang;CHEN Ming;ZHANG Yu-qiang(Department of Chemical Engineering,Sichuan University,Chengdu 610065,Sichuan Province,China)

机构地区：[1]四川大学化学工程学院,四川成都610065

出　　处：《化学工程》2018年第7期63-66,共4页Chemical Engineering(China)

基　　金：四川大学科技计划项目磷化工关键技术与产业化资助项目(SCU2015C002)

摘　　要：在磷酸三丁酯合成过程中,氯丁烷的反应动力学研究对提高磷酸三丁酯的收率具有非常重要的意义。通过氯丁烷的反应动力学研究可以优化反应条件,提高磷酸三丁酯合成过程中的收率。文中考察了反应温度,反应物浓度对氯丁烷合成的影响。通过微分法确定了正丁醇与氯化氢的反应为二级反应,表观活化能为48.37 kJ/mol,指前因子为2 357.1 L/(mol·min),并得到了表观反应动力学方程。通过比较验证,动力学模型计算值与实验值相接近,可为磷酸三丁酯反应过程的模拟提供动力学数据。In the production process of tributyl phosphate, the research of reaction kinetics of n -butyl chloride is a great significance to increase the yield of tributyl phosphate. Through kinetic study on the reaction of butyl chloride synthesis, the optimum production process conditions were determined. The effects of temperature and the initial concentration of hydrogen chloride and butanol on the synthesis were investigated. The reaction is a second-order reaction calculating with the differential method. The apparent kinetic equation is obtained where its apparent activation energy is 48.37 kJ/mol and its pre-exponential factor is 2 357.1 L/ （mol·min）. By comparison verification it could be found that the dynamic model values calculated were in good agreement with the experimental values, which could provide kinetic data to the preparation of tributyl phosphate.

关 键 词：氯丁烷 反应动力学 磷酸三丁酯 

分 类 号：TQ031.2[化学工程]