Development a Spectrophotometric of Fe(Ⅲ), Al(Ⅲ) and Cu(Ⅱ) Using Eriochrome Cyanine R Ligand and Assessment of the Obtained Data by Partial Least-Squares and Artificial Neural Network Method-Application to Natural Waters  

作　　者：A. Hakan AKTAS 

机构地区：[1]Department of Chemistry, Faculty of Science & Art, Suleyman Demirel University, Isparta 32260, Turkey

出　　处：《光谱学与光谱分析》2018年第8期2638-2644,共7页Spectroscopy and Spectral Analysis

摘　　要：Simultaneous determination of heavy metal cations and accurate quantitative prediction of them are of great interest in analytical chemistry.This work has focused on a comprehensive comparison of partial least squares(PLS-1)and artificial neural networks(ANN)as two types of chemometric methods.For this purpose,aluminum,iron and copper were studied as three analytes whose UV-Vis absorption spectra highly overlap each other.Accordance with determined parameters(ligand concentration,pH,waiting times,the relationship between absorbance and concentration of metal ion effect and foreign ions)are provided and the optimum conditions.After establishing the optimum conditions for Fe^(3+),Al^(3+) and Cu^(2+) containing mixtures spectrophotometric determinations and the data calibration method of least squares(PLS-1)regression,and artificial neural network(ANN)methods were used.Chemometric methods are applied in a fast,simple,and the results are applicable.Simultaneous determination of heavy metal cations and accurate quantitative prediction of them are of great interest in analytical chemistry. This work has focused on a comprehensive comparison of partial least squares （PLS-1） and artificial neural networks （ANN） as two types of chemometric methods. For this purpose, aluminum, iron and copper were studied as three analytes whose UV-Vis absorption spectra highly overlap each other. Accordance with determined parameters （ligand concentration, pH, waiting times, the relationship between absorbance and concentration of metal ion effect and foreign ions） are provided and the optimum conditions. After establishing the optimum conditions for Fe3＋, Al3＋ and Cu2＋ containing mixtures spectrophotometric determinations and the data calibration method of least squares （PLS-1） regression, and artificial neural network （ANN） methods were used. Chemometric methods are applied in a fast, simple, and the results are applicable.

关 键 词：UV-Vis spectrophotometry Partial least squares Artificial neural network ALUMINUM IRON COPPER 

分 类 号：O657.3[理学—分析化学]