Co-NH_2-SBA-15的制备及其脱硫性能研究  

Preparation of Co-NH_2-SBA-15 and its performance of desulphurization

作　　者：陈颖[1] 韩书宇 梁宇宁[1] 高彦华[1] 丛书丽 CHEN Ying , HAN Shu-yu, LIANG Yu-ning, GAO Yan-hua, CONG Shu-li(Provincial Key Laboratory of Oil ＆Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, Chin)

机构地区：[1]东北石油大学石油与天然气化工省重点实验室,黑龙江大庆163318

出　　处：《燃料化学学报》2018年第6期754-761,共8页Journal of Fuel Chemistry and Technology

基　　金：国家自然科学基金(50476091)资助~~

摘　　要：采用水热合成法制备介孔分子筛SBA-15,用(CH3COO)_2Co对其进行超声浸渍改性,并用硅烷偶联剂APTS将氨基引入SBA-15分子筛中,制备出Co-NH_2-SBA-15吸附剂,考察了常温条件下H2S的吸附性能。通过SEM、XRD、FT-IR、BET、XPS等表征手段对吸附剂进行表征。结果表明,氨基与金属同时负载在分子筛表面,氨基与硅物质的量比为0.20,Co负载质量分数为8%的SBA-15吸附效果最好,当原料气H_2S体积分数为227μL/L,温度25℃,气体流量75 mL/min时,穿透硫容和饱和硫容达0.151和0.190 mmol/g,且吸附剂可再生利用。SBA-15表面嫁接氨基并浸渍金属改性的手段不仅提高了吸附容量,同时提高了分子筛的稳定性。The mesoporous molecular sieve SBA-15 was prepared by hydrothermal synthesis,modified with the ultrasonic immersion by（ CH3COO）2Co and with the introduction of the amino group into it with APTS as silane coupling agent,and characterized by SEM,XRD,FT-IR,BET and XPS. The prepared Co-NH_2-SBA-15 was used for adsorption of H2S at normal temperature. The results showthat both amino group and metal have been introduced into the molecular sieve. When the molar ratio of amino group to silicon is 0.20 and the Co loading is8%,the adsorption capacity of SBA-15 is the highest. Under the conditions of the volume fraction of hydrogen sulfide of 227 μL/L, the temperature of 25 ℃ and the gas flowrate of 75 mL/min, the capacities of breakthrough sulfur and saturated sulfur come to 0.151 and 0.190 mmol/g,respectively. Moreover,the adsorbent can be regenerated for recycle. Under the assistance of molecular sieve surface being grafted by amino group and impregnated by metal,the adsorption capacity can be improved and the stability of molecular sieve can be enhanced.

关 键 词：SBA-15 改性 APTS H2S吸附 

分 类 号：TE626[石油与天然气工程—油气加工工程]