3-氨基-4-偕氨肟基呋咱及其含能衍生物合成研究进展  

Research Progress on Synthesis of 3-Amino-4-aminoximiofurazan and Its Energetic Derivatives

作　　者：王彬[1] 周彦水[1] 吴敏杰[1] 李普瑞[1] 李亚南[1] 王伯周[1] WANG Bin;ZHOU Yan-shui;WU Min-jie;LI Pu-rui;LI Ya-nan;WANG Bo-zhou(Xi’an Modern Chemistry Research Institute,Xi’an 710065,China)

机构地区：[1]西安近代化学研究所,陕西西安710065

出　　处：《火炸药学报》2018年第3期213-222,共10页Chinese Journal of Explosives & Propellants

基　　金：国家自然科学基金(No.21373157)

摘　　要：综述了3-氨基-4-偕氨肟基呋咱(AAOF)的几种典型合成方法;基于AAOF分子结构中氨基、偕氨肟基的反应活性,可合成3,4-双(4′-氨基呋咱-3′-基)氧化呋咱(DATF)、3,4-双(4′-硝基呋咱-3′-基)氧化呋咱(DNTF)、3,4-双(4′-叠氮基呋咱-3′-基)氧化呋咱(DAZTF)、呋咱胺含能化合物、呋咱醚(FOF-2、FOF-13、BFFO、TFO)等典型含能化合物。系统介绍了上述8大系列30种高含能化合物的合成技术途径及主要的物化性能,有望在高能炸药、高能推进剂等领域得到应用。附参考文献56篇。Several typical synthetic methods of 3-amino-4-aminoximiofurazan（AAOF）were reviewed.Based on the reaction activity of amino and amidoximo group in the AAOF,typical energetic compounds such as 3,4-bis（4′-aminofurazano-3′）furoxan（DATF）,3,4-bis（4′-nitrofurazan-3′-yl）furoxan（DNTF）,3,4-bis（4′-azidofurazano-3′-yl）furoxan（DAZTF）,furazan amine energetic compounds and furazan ethers（FOF-2,FOF-13,BFFO,TFO）etc.can be synthesized.The synthetic technology and main physicochemical properties of the above eight series,thirty kinds of high energetic compounds,were systematically introduced and are expected to be applied in the fields of high energy explosives and high energy propellants.56 References are attached.

关 键 词：3-氨基-4-偕氨肟基呋咱 AAOF 呋咱含能衍生物 高能量密度化合物 呋咱胺 呋咱醚 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] O62[理学—有机化学]