Preparation of Aminated Lignin through Etherification and Amination  

作　　者：ChangZhou Chen BingXin Wang YanRu Zhang Ting Shi Jun Liu XiLuan Wang YongMing Fan 

机构地区：[1]College of Material Science and Technology, Beijing Forestry University,Beijing,100083,China

出　　处：《Paper And Biomaterials》2018年第2期16-23,共8页造纸与生物质材料（英文）

基　　金：supported by the Research Project for Hot Tracking Items of Beijing Forestry University(2017BLRD03);the National Natural Science Foundation of China(51603012);the Special Science and Technology Research Program of Beijing Forestry University(2016KJ02);the Fundamental Research Funds for the Central Universities(BLYJ2016-17,BLX2015-06)

摘　　要：A new method for the preparation of aminated lignin （AEL） through etherification and amination reaction was presented. Chlorine atoms were ？rstly introduced into lignin through its etheri？cation with epichlorohydrin. Then, hydrophilic amine groups were grafted to the modi？ed lignin structure through amination with ethylenediamine to obtain AEL. Subsequent acidi？cation of AEL led to the ionized aminated lignin （IAEL）. The results of our analyses showed that the nitrogen content of AEL was 6.9%. Foaming and emulsifying experiments indicated that AEL had better foamability and emulsifying properties than IAEL. Surface tension tests showed that AEL and IAEL had similar critical micelle concentration （CMC）. However, IAEL had lower surface tension （36.33 mN/m） than AEL （42.89 mN/m） at CMC. These results demonstrate the promising applicability of AEL as an emulsi？er and that of IAEL as feedstock in the production of detergent and dispersant.A new method for the preparation of aminated lignin(AEL) through etherification and amination reaction was presented. Chlorine atoms were firstly introduced into lignin through its etherification with epichlorohydrin. Then, hydrophilic amine groups were grafted to the modified lignin structure through amination with ethylenediamine to obtain AEL. Subsequent acidification of AEL led to the ionized aminated lignin(IAEL). The results of our analyses showed that the nitrogen content of AEL was 6.9%. Foaming and emulsifying experiments indicated that AEL had better foamability and emulsifying properties than IAEL. Surface tension tests showed that AEL and IAEL had similar critical micelle concentration(CMC). However, IAEL had lower surface tension(36.33 mN/m) than AEL(42.89 mN/m) at CMC. These results demonstrate the promising applicability of AEL as an emulsifier and that of IAEL as feedstock in the production of detergent and dispersant.

关 键 词：LIGNIN ETHERIFICATION AMINATION EPICHLOROHYDRIN ETHYLENEDIAMINE 

分 类 号：O623.731[理学—有机化学] X793.03[理学—化学]