IRMOF-1衍生介孔ZnO微球催化合成低聚聚碳酸酯二醇  

Synthesis of Oligomeric Polycarbonate Diol Catalyized by Mesoporous ZnO Microspheres derived from IRMOF-1

作　　者：王丽苹 赵粒成 张林艳 Wang Liping;Zhao Licheng;Zhang Linyan(College of Chemistry and environmental science,Qujing Normal University,Qujing 655011,China)

机构地区：[1]曲靖师范学院化学与环境科学学院,曲靖655011

出　　处：《化学通报》2018年第8期705-712,共8页Chemistry

基　　金：云南省应用基础研究计划项目(2013FZ108)资助

摘　　要：IRMOF-1是一种最经典的IRMOF系列材料,通过直接在空气中不同温度下热处理IRMOF-1得到三种ZnO催化剂,并采用XRD、SEM、BET、CO_2-TPD等分析技术对所得样品的晶体结构、表观形貌、孔结构、表面碱性进行了表征。结果显示,ZnO为球状结构,是一种典型的介孔材料,BET比表面积和孔径分别为49.7~62.2 m2/g和2.18~2.92 nm。研究了ZnO微球在碳酸二苯酯(DPC)与新戊二醇(NPG)酯交换合成低聚碳酸酯二醇(PCDL)反应中的催化性能。结果表明,500℃下得到的ZnO微球在DPC与NPG酯交换反应中表现出良好的催化活性。IRMOF-1 is one of the most classic IRMOF series MOFs materials. Three ZnO catalysts were prepared by heat treatment of IRMOF-1 directly in air at different temperatures, and the crystal structure,morphology,pore structure and surface alkalinity of the samples were characterized by XRD, SEM, BET measurements and CO2-TPD. The results showed that as-prepared ZnO are a typical mesoporous material with spherical structure,their BET surfcae area and pore size are 49. 7 - 62. 2 m2/g and 2. 18 - 2. 92 nm,respectively.The catalytic activities of mesoporous ZnO microspheres for the synthesis polycarbnate diol via diphenyl carbonate and neopentyl glycol（ NPG） were investigated. The results exhibited that the ZnO microspheres obtained at 500 ℃exhibit good catalytic activity in the transesterification of DPC and NPG.

关 键 词：金属有机骨架材料 氧化锌 催化 聚碳酸酯二醇 酯交换 

分 类 号：O631.5[理学—高分子化学]