两种对氯苯磺酰谷氨酸锌(Ⅱ)配合物的合成与性能研究  

Synthesis and Properties of Two Zn(Ⅱ) Complexes With p-Chlorobenzenesulfonylglutamate

作　　者：刘峥军[1,2] 陈晓淼 刘凌云[1,2] LIU Zheng-jun;CHEN Xiao-miao;LIU Ling-yun(Special and Key Laboratory of Functional Materials and Resource Chemistry,Anshun University,Guizhou Anshun 561000,China;School of Chemistry and Chemical Engineering,Anshun College,Guizhou Anshun561000,China)

机构地区：[1]安顺学院.贵州省教育厅功能材料与资源化学特色重点实验室,贵州安顺561000 [2]安顺学院化学化工学院,贵州安顺561000

出　　处：《辽宁化工》2018年第7期623-624,680,共3页Liaoning Chemical Industry

基　　金：贵州省科技厅三方联合基金项目;项目号:黔科合LH字【2014】7499;贵州省教育厅重点项目;项目号:黔教合KY字[2015]385;安顺学院平台项目;项目号:2015PT03

摘　　要：以对氯苯磺酰谷氨酸为第一配体,分别以邻菲罗啉和4,4'-联吡啶为第二配体,采用溶剂热合成法合成对氯苯磺酰谷氨酸·邻菲罗啉合锌(Ⅱ)和对氯苯磺酰谷氨酸·(4,4'-联吡啶)合锌(Ⅱ)两个配合物,通过红外光谱初步确定成功合成得到了两个目标配合物,并通过荧光光谱测试了其发光性能。Two complexes of p-chlorobenzenesulfonylglutamate·phenanthroline zinc（Ⅱ） and p-chlorobenzenesulfonylglutamate·（4,4＇-bipyridyl） zinc（Ⅱ） were synthesized with p-chlorobenzenesulfonyl glutamate as the first ligand and phenanthroline and 4,4＇-bipyridyl as the second ligand respectively by the solvothermal synthesis method. The complexes were characterized by infrared spectroscopy,and their luminescence properties were tested by fluorescence spectroscopy.

关 键 词：对氯苯磺酰谷氨酸 邻菲罗啉 4 4'-联吡啶 锌 配合物 

分 类 号：O641.4[理学—物理化学]