国内外含能配位聚合物最新研究进展  

Latest Progress in Research on Energetic Coordination Polymers at Home and Abroad

作　　者：刘雪敏 刘红利[1] 高潮[1] 郭兆琦[1,3] LIU Xue rain;LIU Hong-li;GAO Chao;GUO Zhao qi(Xi＇an Modern Chemistry Research Institute,Xi＇an 710065,China;College of Chemistry Materials Science,Northwest University,Xi＇an 710127,China;School of Chemical Engineering Northwest University,Xi＇an 710069,China)

机构地区：[1]西安近代化学研究所,陕西西安710065 [2]西北大学化学与材料科学学院,陕西西安710127 [3]西北大学化工学院,陕西西安710069

出　　处：《火炸药学报》2018年第2期107-116,共10页Chinese Journal of Explosives & Propellants

基　　金：国家自然科学基金(No.21504067)

摘　　要：为了阐明含能配位聚合物(Energetic Coordination Polymers,ECPs)结构与其性能的关系,分别从ECPs结构中的电荷状态和潜在应用两方面综述近几年发表的研究成果。在叙述中性离子、阳离子和阴离子ECPs时,又按照配体进行分类,综述了配位聚合物的晶体结构,及其密度、热稳定性、能量和感度等性能参数,归纳了ECPs结构与性能的关系。按照配位聚合物的结构特点和性能,探讨了其作为起爆药、炸药和燃速调节剂的潜在应用。分析了相关研究中未解决的问题,包括高金属含量导致能量降低、密度泛函方法计算的能量值的可靠性、尚无系统研究实测能量值等。提出今后的研究重点应是按照应用方向开发性能优良的ECPs。附参考文献50篇。To illustrate the structure property relationship of energetic coordination polymers （ECPs） , the research results published in recent years are reviewed from two aspects of the charge state and potential application in the structure of ECPs, respectively. When ECPs with neutral ion, cation and anion are described, ECPs are classified according to ligands. The crystal structures, density, thermal stability, energy and sensitivity for coordination poly mers are reviewed and the structure property relationships of ECPs are summarized. The potential application of ECPs as primary explosives, second explosives and burning rate regulators are discussed according to their structural characteristics and properties. Some unsolved problems in the related research, including reducing energy due to high metal content, reliability of energy value calculated by DFT method and the urgent of confirm energy by experi mental measurements, are analyzed. It is proposed that the focus of future research is to develop the ECPs with ex cellent properties according to the application direction with 50 references.

关 键 词：含能材料 配位聚合物 ECPs 起爆药 燃速调节剂 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] O63[理学—高分子化学]