硬脂酸表面改性对聚氨酯发泡法制备ZrO2多孔陶瓷性能的影响  

Effects of Stearic Acid Modification on Properties of ZrO2 Porous Ceramics Prepared by Polyurethane Foaming Method

作　　者：唐欣悦 张在娟 霍文龙 张笑妍 刘静静 闫姝 王修慧[1] 杨金龙[1,2] TANG Xinyue;ZHANG Zaijuan;HUO Wenlong;ZHANG Xiaoyan;LIU Jingjiing;YAN Shu;WANG Xiuhui;YANG Jinlong(School of Materials Science and Engineering,Dalian Jiaotong University,Dalian 116028,China;State Key Laboratory of New Ceramics and Fine Processing,School of Materials Science and Engineering,Tsinghua University,Beijing 100084,China)

机构地区：[1]大连交通大学材料科学与工程学院,辽宁大连116021 [2]清华大学材料学院,新型陶瓷与精细工艺国家重点实验室,北京100084

出　　处：《硅酸盐学报》2018年第6期772-779,共8页Journal of The Chinese Ceramic Society

基　　金：国家自然科学基金(51702184);中国博士后科学基金(2017M610085)资助

摘　　要：通过聚氨酯发泡法制备了ZrO2多孔陶瓷,研究了ZrO2粉体表面改性对多孔陶瓷综合性能的影响。结果表明：ZrO2粉体表面进行硬脂酸改性不仅可以阻止颗粒团聚,有效降低浆料黏度,并显著提高粉体表面的亲油性,增加粉体与有机聚氨酯原料的相容性,还可增加粉体与聚氨酯官能团的相互作用,促进聚氨酯交联网络形成,进而解决坯体及多孔陶瓷的分层问题,提高ZrO2多孔陶瓷的力学性能。当使用0.75%硬脂酸改性的ZrO2粉体时,所得多孔陶瓷无分层,孔结构完整,其抗压强度明显增加,为未改性ZrO2粉体所得多孔陶瓷的3倍。This paper was to investigate the preparation of porous ZrO2 ceramic via the expansion of a ceramic suspension by polyurethane（PU） foam system. The effect of stearic acid modification on the properties of porous ceramic was investigated. The results show that the compatibility of the system is improved due to the enhancement of hydrophobicity, the agglomeration of particles is restrained, the viscosity of the slurry is decreased and the formation of network is promoted due to the interaction between ceramic powders and functional groups of polyurethane after the modification. The addition of stearic acid can solve the delamination problem of green body and improve the mechanical properties of ZrO2 ceramic. When the addition of stearic acid is 0.75%, ZrO2 ceramic has good mechanical properties due to the complete pore structure with no delamination. The compressive strength of modified ZrO2 ceramic is three times greater than that of unmodified ZrO2 ceramic.

关 键 词：改性 聚氨酯 氧化锆 多孔陶瓷 

分 类 号：TQ172.75[化学工程—水泥工业]