Synthetic Strategies for Constructing Two-Dimensional Metal-Organic Layers （MOLs）： A Tutorial Review  

作　　者：Lingyun Cao Tingting Wang Cheng Wang 

机构地区：[1]Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, China

出　　处：《Chinese Journal of Chemistry》2018年第8期754-764,共11页中国化学（英文版）

基　　金：The present research was financialiy supported by the National Natural Science Foundation of China （Nos. 21671162, 21471126）, Ministry of Science and Technology of China （2016YFA0200700） and the National Thousand Talents Program of China.

摘　　要：Two-dimensional （2D） metal-organic layers （MOLs） are the 2D version of metal-organic frameworks （MOFs） with nanometer thickness in one dimension. MOLs are also known as 2D-MOFs, 2D coordination polymers, ultrathin MOF nanosheets （UMOFNs） or coordination nanosheets in literature. This new category of 2D materials has attracted a lot of interests because of the opportunity in combining molecular chemistry, surface/interface chemistry and material chemistry of low dimensional materials in these systems. Several synthetic strategies have been developed for the construction of 2D MOLs, but the general synthesis of MOLs still presents a challenge. This tutorial level review summarizes the recent progress in the fabrication of novel 2D MOLs and aims to highlight challenges in this field.Two-dimensional （2D） metal-organic layers （MOLs） are the 2D version of metal-organic frameworks （MOFs） with nanometer thickness in one dimension. MOLs are also known as 2D-MOFs, 2D coordination polymers, ultrathin MOF nanosheets （UMOFNs） or coordination nanosheets in literature. This new category of 2D materials has attracted a lot of interests because of the opportunity in combining molecular chemistry, surface/interface chemistry and material chemistry of low dimensional materials in these systems. Several synthetic strategies have been developed for the construction of 2D MOLs, but the general synthesis of MOLs still presents a challenge. This tutorial level review summarizes the recent progress in the fabrication of novel 2D MOLs and aims to highlight challenges in this field.

关 键 词：metal-organic layers metal-organic frameworks 2D materials bottom-up synthesis top-down synthesis 

分 类 号：TB91[一般工业技术—计量学] S512.1[机械工程—测试计量技术及仪器]