乙醇Guerbet缩合合成正丁醇反应催化剂性能的研究进展  

Progress of Catalyst Research for n-Butanol Synthesis via Ethanol Guerbet Condensation

作　　者：朱雄华 安华良[1] 赵新强[1] 王延吉[1] ZHU Xiong-hua;AN Hua-liang;ZHAO Xin-qiang;WANG Yan-ji(Hebei Provincial Key Laboratory of Green Chemical Technology and Efficient Energy Saving,School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130,China)

机构地区：[1]河北工业大学化工学院,绿色化工与高效节能河北省重点实验室,天津300130

出　　处：《高校化学工程学报》2018年第4期748-757,共10页Journal of Chemical Engineering of Chinese Universities

基　　金：国家自然科学基金(21476058,21506046); 天津市自然科学基金青年项目(16JCQNJC06100)

摘　　要：由于生物丁醇比生物乙醇具有更高的能量密度和燃油效率,能与汽油以任意比混合、对发动机和管路无腐蚀性,因此生物丁醇更适宜作为日益枯竭的化石燃料的替代品。乙醇Guerbet缩合反应合成正丁醇具有原料来源广、工艺流程短、环境友好等优点,因而受到国内外广泛关注。作者系统比较了用于乙醇Guerbet缩合合成正丁醇反应催化剂的性能,并对今后催化剂的研究方向进行了展望。Biobutanol has higher energy density and fuel efficiency than bioethanol, and it can blend with gasoline in any proportion without corroding engine and pipeline. Therefore, biobutanol is a potential candidate for replacing fossil fuels. n-Butanol synthesis via ethanol Guerbet reaction attracts extensive attention for its advantages of wide raw materials supply, short process and environmental-friendliness. In this paper, the performance of catalysts for this reaction is discussed and future research is prospected.

关 键 词：乙醇 Cuerbet缩合 正丁醇 催化剂 

分 类 号：TQ032[化学工程]