脂肪族聚碳酸酯的研究进展  

Research Progress of Aliphatic Polycarbonates

作　　者：王伟文[1] 阴鸿玉 张自生[1] WANG Wei-wen;YIN Hong-yu;ZHANG Zi-sheng(Qingdao University of Science ＆ Technology,Shandong Qingdao 266042,China)

机构地区：[1]青岛科技大学,山东青岛266042

出　　处：《当代化工》2018年第8期1709-1712,共4页Contemporary Chemical Industry

基　　金：山东省重点研发计划(2016GSF110729);青岛市科技成果转化计划-科技惠民专项(16-6-2-50-nsh)

摘　　要：由于聚碳酸酯产品市场的快速增长,因此聚碳酸酯是一个极具开发前景的产品。脂肪族聚碳酸酯具有很好的生物相容性、生物降解性。阐述了脂肪族聚碳酸酯的合成方法,包括光气法、二氧化碳与环氧化物共聚法、环状碳酸酯开环聚合法、酯交换法四种,以及四种方法的研究进展,并对脂肪族聚碳酸酯以后的发展进行展望。Due to the rapid growth of polycarbonate market, the polycarbonate becomes a highly promising product.Aliphatic polycarbonate has good biocompatibility and biodegradability. In this article, the synthesis methods of aliphatic polycarbonates were introduced, including phosgene method, copolymerization method of carbon dioxide with epoxides, ring-opening polymerization method of cyclic carbonates, transesterification method of dialkyl carbonate with diols, and research progress of the four synthesis methods was discussed. The future development trend of aliphatic polycarbonates was prospected.

关 键 词：脂肪族聚碳酸酯 生物降解性 合成方法 

分 类 号：TQ323.41[化学工程—合成树脂塑料工业]