白光发射超分子水凝胶的构筑和发光性能研究  

Construction and Luminescent Behavior of Supramolecular Hydrogel with White-Light Emission

作　　者：张依 陈湧[1] 李晶晶 梁璐 刘育[1,2] Zhang Yi;Chen Yong;Li Jingjing;Liang Lu;Liu Yu(State Key Laboratory of Elemento-Organic Chemistry,College of Chemistry,Nankai University,Tianjin 300071;Collaborative Innovation Center of Chemical Science and Engineering（Tianjin）,Nankai University,Tianjin 300072)

机构地区：[1]元素有机化学国家重点实验室,南开大学化学学院,天津300071 [2]天津化学化工协同创新中心,天津300072

出　　处：《化学学报》2018年第8期622-626,共5页Acta Chimica Sinica

基　　金：国家自然科学基金(Nos.21432004,21672113,21772099,21861132001 and 91527301)资助

摘　　要：具有白光发射性质且发光可调的超分子水凝胶在发光材料和荧光检测领域具有广泛的应用前景.采用双(2-氨基丙基醚)聚丙二醇(PPG-NH_2)链穿线带有正电荷的6-乙二胺修饰β-环糊精构成准轮烷,进而与锂皂石作用构筑了超分子水凝胶,并通过流变、zeta电势和扫描电镜等手段对凝胶性质进行了表征.当将扭曲分子内电荷转移(TICT)型的有机染料分子硫黄素T(ThT)和碘化4-[4-(二甲基氨基)苯乙烯基]-1-甲基吡啶鎓(DASPI)引入到水凝胶中,这两种有机染料能够在凝胶相中发生荧光共振能量转移(FRET),从而产生包括白光在内的不同颜色的荧光发射.本研究为水基超分子发光软材料提供了一种新的构筑方法.Color-tunable luminescent supramolecular hydrogel with white-light emission is widely applied in the fields of light-emitting materials and fluorescence sensors due to their good physicochemical and biochemical properties. Using β-cyclodextrin, a class of cyclic oligosaccharide with seven D-glucose units linked by α-1,4-glucose bonds, and laponite as staring materials, we herein developed a photo-luminescent supramolecular hydrogel from laponite and pseudorotaxane that was constructed by the threading of ethylenediamine-modified β-cyclodextrins onto the poly（propylene glycol） bis（2-amionopropylether）（PPG-NH2） chain. The supramolecular hydrogel properties thus obtained were characterized by rheological experiments, zeta potential measurements and scanning electron microscopy（SEM）. The results showed that the supramolecular hydrogel possessed satisfactory mechanical properties, negative charges and porous three-dimensional structure. Then, thioflavin T（Th T） and 4-（4-dimethylaminostyryl）-1-methylpyridinium（DASPI）, two typical distorted intramolecular charge transfer（TICT） molecules with dramatically increased fluorescence when the molecules are in confined region, were selected as model substrates. Generally, Th T and DASPI had almost no fluorescent emission at an excitation wavelength of 412 nm. By comparing the normalized fluorescence emission spectrum of Th T and the UV-visible absorption spectrum of DASPI, we found that the UV-Vis absorption band of DASPI showed a good overlap with the fluorescence emission band of Th T. Therefore, the fluorescence resonance energy transfer（FRET） process would occur between Th T and DASPI in the laponite/pseudorotaxane supermolecular hydrogel phase, where Th T acted as an energy donor and DASPI acted as an energy receptor. Then the fluorescence behavior of Th T/DASPI pairs in the supramolecular hydrogel phase was investigated. The results showed, after two TICT dyes, Th T and DASPI, were introduced in the hydrogel, the efficient FRET betwe

关 键 词：超分子水凝胶 多色荧光 白光发射 环糊精 准轮烷 

分 类 号：O648.17[理学—物理化学]