邻甲酚醛环氧树脂与4,4’-二氨基二苯甲烷固化反应研究  

Curing Reaction of o-Cresol Formaldehyde Epoxy Resin with 4,4'-Diaminodiphenyl Methane as Cure Agent

作　　者：曹翔 梁天 杨世刚 张源源 童志伟[1] Cao Xiang;Ling Tian;Yang Shigang(School of Chemical Engineering,Huaihai Institute of Technology,Jiangsu Lianyungang 222005;Jiangsu Sanjili Chemical Co.,Ltd,Jiangsu Lianyungang 222066)

机构地区：[1]淮海工学院化工工程学院,江苏连云港215005 [2]江苏三吉利化工股份有限公司,江苏连云港222066

出　　处：《化工时刊》2018年第8期1-3,共3页Chemical Industry Times

基　　金：连云港市产业前瞻与共性关键技术(CG1602);连云港"海燕计划"资助项目;江苏省大学生实践创新训练计划项目

摘　　要：以4,4'二氨基二苯甲烷作为固化剂对邻甲酚醛环氧树脂进行固化反应研究,使用差示扫描量热法对固化热力学研究,通过Kissinger法测得固化反应表观活化能Ea为52.70kJ/mol,用Flynn-Wall-Ozawa测得非等温固化反应活化能为56.929kJ/mol。此外,用傅里叶变换红外光谱对固化反应历程进行了探讨,用热分析法对固化树脂的热分解动力学进行研究,固化产物在动态N2气氛下热降解机理为一级反应模式。The o-cresol formaldehyde resinwas cured with 4,4＇-diaminodiphenylmethanecuring agent.The curing reaction kineticswas studied by differential scanning calorimetry.The apparent activation energy of curing reaction Ea was 52.70 k J/mol and the activation energy of non-isothermal curing reaction with Flynn-Wall-Ozawa was56.929 k J/mol.The curing reaction process was studied by Fourier transform infrared spectroscopy.Thermal analysiswas used to study the decomposition kinetics of the cure resin.

关 键 词：4 4'二氨基二苯甲烷 邻甲酚醛环氧树脂 固化反应动力学 热降解动力学 

分 类 号：TQ323.5[化学工程—合成树脂塑料工业]