水溶性柱[6]芳烃与1,1'-双取代二茂铁衍生物的主-客体作用研究  

Host-Guest Interaction between Water-Soluble Pillar[6]arene and 1,1'-Disubstituted Ferrocene Derivatives

作　　者：李臻益 候娜娜[1] 邵为 肖守军[1] 林晨[1] 王乐勇[1] Li Zhenyi;Hou Nana;Shao Wei;Xiao Shoujun;Lin Chen;Wang Leyong(School of Chemistry and Chmeical Engineering,Nanjing University,Nanjing 210046)

机构地区：[1]南京大学化学化工学院,南京210046

出　　处：《有机化学》2018年第8期2002-2007,共6页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(Nos.21672102;21572101)资助项目~~

摘　　要：基于单取代二茂铁与柱芳烃主体大环分子构筑的超分子功能体系在诸多领域中已经取得了较好的进展.对1,1'-双取代二茂铁衍生物与水溶性柱[6]芳烃的主-客体作用进行了初步的探索与研究,为以后开展基于双取代二茂铁衍生物与水溶性柱[6]芳烃的轮烷、准轮烷体系以及其他相关超分子功能体系奠定基础.The supramolecular functional system based on host-guet interaction between monosubstituted ferrocene derivatives and pillararene-based macromolecule molecules has made impressive progress in many different fields. The host-guet interaction between 1,1＇-disubstituted ferrocene derivatives and water-soluble pillar[6]arene was preliminarily explored and studied. This work may give some support for the subsequent development of supramolecular functional systems,such as rotaxane, pseudorotaxane systems, based on the host-guet interaction between 1,1＇-disubstituted ferrocene derivatives and water-soluble pillar[6]arene.

关 键 词：芳烃 双取代二茂铁衍生物 主-客体作用 

分 类 号：O627.81[理学—有机化学]